diphenylbismuth 2,4-dimethylbenzenesulfonate | 329055-56-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenylbismuth 2,4-dimethylbenzenesulfonate
• 英文别名: Diphenylbismuthanyl 2,4-dimethylbenzenesulfonate
• CAS: 329055-56-3
• 化学式: C₂₀H₁₉BiO₃S
• 分子量: 548.415
• InChiKey: VOLCEZNHONNJRY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.81
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  diphenylbismuth 2,4-dimethylbenzenesulfonate 、 溴 以 乙醚 为溶剂， 以78%的产率得到tetraphenylbismuth(V) 2,5-dimethylbenzenesulfonate
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1023475615290
• 作为产物：
  描述：

  2,4-二甲基苯磺酸 、 三苯基铋 以 乙醚 为溶剂， 以95%的产率得到diphenylbismuth 2,4-dimethylbenzenesulfonate
  参考文献：
  名称：

  Sharutin; Sharutina; Zhitkevich, Russian Journal of General Chemistry, 2000, vol. 70, # 5, p. 687 - 689

  摘要：

  DOI：

文献信息

• ——
  作者：V. V. Sharutin、O. K. Sharutina、I. I. Pavlushkina、I. V. Egorova、A. P. Pakusina、D. B. Krivolapov、A. T. Gubaidullin、I. A. Litvinov

  DOI：10.1023/a:1012385524010

  日期：——

  Tetraphenylantimony arenesulfonates and diphenylbismuth arenesulfonates were prepared by reaction of triphenylbismuth bis(arenesulfonates) with triphenylstibine in toluene at 25 degreesC. The crystal and molecular structure of diphenylbismuth 2,4-dimethylbenzenesulfonate was studied by single crystal X-ray diffraction. The molecules of the compound in the crystal form chains of Ph2BiOSO2C6H3Me2-2,4 fragments linked with oxygen atoms of the sulfo group of the bridging arenesulfonate ligand.
• ——
  作者：V. V. Sharutin

  DOI：10.1023/a:1023463212564

  日期：——

  Pentaarylantimony Ar3Sb (Ar = Ph, p-Tol) arylates diarylbismuth arylsulfonates Ar2BiOSO2Ar' (Ar' = C6H4Me-4; C6H3Me2-2,4, C6H3Me2-2,5) in ether at 20 degreesC (48 h) to form triarylbismuth in yields of up to 95%. The second reaction product is tetraarylantimony arenesulfonate. The reaction of pentaphenylantimony with phenylbismuth bis(arenesulfonate) PhBi(OSO2Ar')(2) under the same conditions leads to formation of diphenylbismuth arenesulfonate and tetraphenylantimony arenesulfonate in yields of up to 90%.
• ——
  作者：V. V. Sharutin

  DOI：10.1023/a:1023619616897

  日期：——

  Tetraphenylbismuth 2,4-dimethylbenzenesulfonate was synthesized by reacting pentaphenylbismuth or bromine with diphenylbismuth 2,4-dimethylbenzenesulfonate and its structure was established using X-ray diffraction analysis. The Bi atom has a distorted trigonal bipyramidal coordination. The Bi-C bond lengths are equal to 2.199(4)-2.227(4) Angstrom; the Bi-O distance and axial CBiO angle are equal to 2.665(3)degrees and 174.2(1)degrees, respectively.