[Ru(CO)(triphenylarsine)(OC6H4C(CHCHC6H4CH3)O)2] | 1070876-56-0

• 英文名称: [Ru(CO)(triphenylarsine)(OC6H4C(CHCHC6H4CH3)O)2]
• CAS: 1070876-56-0
• 化学式: C₅₁H₄₁AsO₅Ru
• 分子量: 909.875
• InChiKey: YCVFXEGRWNPXFC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [ruthenium(II)(hydride)(chloride)(carbonyl)(triphenylarsine)3] 、 1-(2-羟基苯基)-3-(4-甲基苯基)-2-丙烯-1-酮 以 苯 为溶剂， 以65%的产率得到[Ru(CO)(triphenylarsine)(OC6H4C(CHCHC6H4CH3)O)2]
  参考文献：
  名称：

  Synthesis and spectral characterization of 2′-hydroxy chalconate complexes of ruthenium(II) and their catalytic and biological applications

  摘要：

  The reactions of [RuHCl(CO)(B)(EPh3)(2)] (B = EPh3 or pyridine; E = P or AS) and 2'-hydroxychalcones in 1:2 ratio led to the formation of [Ru(CO)(B)(L)(2)] (B = PPh3, AsPh3 or Py; L = 2'-hydroxychalcones). The new complexes have been characterized by analytical and spectral (IR, electronic and H-1 NMR) data. They have been assigned an octahedral structure. The new complexes were found to catalyze the oxidation of alcohols to aldehydes using N-methylmorpholine-N-oxide as co-oxidant. All the new complexes were found to be active against bacteria such as E. coli, Salmonella typhi and fungi Aspergillus niger. The activity was compared with standard Streptomycin or Bavistin. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.10.043