Ethyl 4-[[1-[2-[(4-ethoxycarbonylphenyl)methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]benzoate

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Ethyl 4-[[1-[2-[(4-ethoxycarbonylphenyl)methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]benzoate
• 化学式: C₄₀H₃₄O₆
• 分子量: 610.706
• InChiKey: ZMCGNYATPOOUHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  46
• 可旋转键数：
  13
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Ethyl 4-[[1-[2-[(4-ethoxycarbonylphenyl)methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]benzoate 在 lithium aluminium tetrahydride 、 三溴化磷 作用下， 以 四氢呋喃 、 二氯甲烷 、 乙腈 为溶剂， 反应 130.0h， 生成
  参考文献：
  名称：

  Synthesis and structural characterization of chiral dicationic imidazolophanes

  摘要：

  Various chiral dicationic benzimidazolophanes were obtained from optically pure (S)-BINOL, benzimidazole and a suitable aryl alkyl dibromide. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.06.159
• 作为产物：
  描述：

  对甲基苯甲酸乙酯 在 N-溴代丁二酰亚胺(NBS) 、 potassium carbonate 作用下， 以 四氯化碳 、 N,N-二甲基甲酰胺 为溶剂， 反应 54.0h， 生成 Ethyl 4-[[1-[2-[(4-ethoxycarbonylphenyl)methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]benzoate
  参考文献：
  名称：

  某些手性单环丁苯橡胶和双环环烷的合成，络合和光异构化研究

  摘要：

  已经合成了具有小的和大的刚性腔的各种手性丁苯橡胶。具有二苯乙烯桥连单元的双环环烷也已经合成。某些芪甲酚与TCNQ或TCNE形成电荷转移络合物。还已经研究了双环烷的光异构化。

  DOI：

  10.1016/j.tet.2007.06.015

文献信息

• Synthesis, complexation, and photoisomerization studies on some chiral monocyclic stilbenophanes and bis-cyclophanes
  作者：Perumal Rajakumar、Subramaniyan Selvam

  DOI：10.1016/j.tet.2007.06.015

  日期：2007.9

  Various chiral stilbenophanes with small and large rigid cavities have been synthesized. Bis-cyclophanes with a stilbene-bridging unit have also been synthesized. Some of the stilbenophanes form charge transfer complexes with either TCNQ or TCNE. Photoisomerization of the bis-cyclophanes has also been studied.

  已经合成了具有小的和大的刚性腔的各种手性丁苯橡胶。具有二苯乙烯桥连单元的双环环烷也已经合成。某些芪甲酚与TCNQ或TCNE形成电荷转移络合物。还已经研究了双环烷的光异构化。
• Synthesis and antibacterial activity of some novel chiral fluorophoric biscyclic macrocycles
  作者：Perumal Rajakumar、Subramaniyan Selvam、Vellaisamy Shanmugaiah、Narayanasamy Mathivanan

  DOI：10.1016/j.bmcl.2006.12.071

  日期：2007.9

  Synthesis of chiral permanent fluorophoric biscyclic macrocycles incorporating anthraquinone and (S)-BINOL core is described. Interestingly, the biscyclic macrocycle I exhibited remarkable antibacterial activity against most of the pathogenic bacteria in the tested concentrations as compared to the other three compounds 2, 14 and 17 as well as the test control, tetracycline. Further biscyclophanes 1 and 2 exhibited permanent. fluorescence sensing property even under highly acidic conditions. (C) 2007 Elsevier Ltd. All rights reserved.
• Synthesis and structural characterization of chiral dicationic imidazolophanes
  作者：Perumal Rajakumar、Subramaniyan Selvam、Manickam Dhanasekaran

  DOI：10.1016/j.tetlet.2005.06.159

  日期：2005.9

  Various chiral dicationic benzimidazolophanes were obtained from optically pure (S)-BINOL, benzimidazole and a suitable aryl alkyl dibromide. (c) 2005 Elsevier Ltd. All rights reserved.