2,6-bis(thiomorpholinomethyl)pyridine | 213403-83-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,6-bis(thiomorpholinomethyl)pyridine
• CAS: 213403-83-9
• 化学式: C₁₅H₂₃N₃S₂
• 分子量: 309.5
• InChiKey: VERNWIUTUUOSNB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.18
• 重原子数：
  20.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  19.37
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  nickel(II) nitrate hexahydrate 、 2,6-bis(thiomorpholinomethyl)pyridine 以 乙腈 为溶剂， 以86%的产率得到dinitrato-2,6-bis(thiomorpholinomethyl)pyridine-nickel(II)
  参考文献：
  名称：

  Synthesis and metal complexes of a chelating ligand containing thiomorpholine and pyridine: 2,6-bis(thiomorpholinomethyl)pyridine

  摘要：

  A chelating ligand, 2,6-bis(thiomorpholinomethyl)pyridine (L), was synthesised. Its palladium(II), copper(II) and nickel(II) complexes of the formula ML(NO3)(2), (M = Pd, Cu and Ni), were prepared and characterised. The molecular structures of the three complexes were determined by X-ray diffraction. In all the compounds prepared the ligand acts in a tridentate fashion using its three N atoms while the two S atoms remain free. The Pd complex possesses a distorted square planar coordination geometry with one of the two nitrate groups coordinating as a unidentate ligand and the other ionic. The Pd-N(pyridine) bond length is 1.857(4) Angstrom, which is believed to be the shortest Pd-N separation ever observed. In the Cu complex, the copper atom is five-coordinated in a distorted square planar arrangement with the two nitrate groups acting as unidentate ligands and occupying the apex and one equatorial position. The Ni complex has a distorted octahedral coordination sphere; one nitrate group behaves in a chelating fashion and the other unidentate. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00132-7