bis[3-(N,N-dimethylamino)propyl]disulfide | 31060-90-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis[3-(N,N-dimethylamino)propyl]disulfide
• 英文别名: bis(3-(dimethylamino)propyl) disulfide；bis-(3-dimethylamino-propyl)-disulfide；Bis-(3-dimethylamino-propyl)-disulfid；bis(N,N-dimethyl-3-aminopropyl)disulfide；Bis-(3-Dimethylamino-1-propyl)-disulfid；3-Dimethylamino-1-propyl-disulfiol；3,3'-Disulfanediylbis(n,n-dimethylpropan-1-amine)；3-[3-(dimethylamino)propyldisulfanyl]-N,N-dimethylpropan-1-amine
• CAS: 31060-90-9
• 化学式: C₁₀H₂₄N₂S₂
• 分子量: 236.446
• InChiKey: IMSAAVCZIMPAKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  57.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis[3-(N,N-dimethylamino)propyl]disulfide 以 甲醇 、 丙酮 、 甲苯 为溶剂， 生成 [Pd(OAc)(SCH2CH2CH2NMe2)]2*H2O
  参考文献：
  名称：

  3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of [Pd(OAc)(ECH2CH2CH2NMe2)]2·H2O (E=S, Se) and [PdCl(TeCH2CH2CH2NMe2)]2

  摘要：

  The reactions of the sodium salts of 3-dimethylamino-l-propylchalcogenolates, prepared by sodium borohydride reduction of (Me2NCH2CH2CH2E)(2) in methanol, with Na2PdCl4 yielded homoleptic [Pd(ECH2CH2CH2NMe2)(2)](6) (1) (E=S (1a); Se (1b); Te (1c)). When treated with [Pd(OAc)(2)](3) or Na2PdCl4, compounds 1 readily gave binuclear redistribution products [PdX(ECH2CH2CH2NMe2))(2) where X = OAc (2) (E = S (2a); Se (2b); or Cl (3)) (E = S (3a); Se (3b); Te (3c)), respectively. The terminal acetate/chloride ligands in 2b/3b can be substituted by other ionic ligands like PhSe-. The complexes were characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy. The structures of 2a, 2b and 3c were established by X-ray crystallography. Each molecule has a dimeric structure in which there are two chalcogenolate bridges from the chelating 3-dimethylamino-l-propylchalcogenolate ligands. On pyrolysis, compound 2b affords Pd17Se15. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.019
• 作为产物：
  描述：

  N,N-二甲氨基氯丙烷盐酸盐 在 硫脲 作用下， 生成 bis[3-(N,N-dimethylamino)propyl]disulfide
  参考文献：
  名称：

  黄原酸酯热重排为二硫代碳酸酯

  摘要：

  在β-二烷基氨基烷基S-甲基黄原酸酯的热解过程中，顺式异构体被全部消除，而dl-反式-2-二甲基氨基环己基S-甲基黄酸酯被重排而不被消除成相应的二硫代碳酸酯。已经提出，连接至带有黄原酸酯基团的碳的二甲基氨基基团引起重排。研究的其他示例也支持这种机制。2-苄酰胺基乙基S-甲基和dl-反式-2-苯甲酰胺基环己基S-甲基黄原酸酯已被转化为相应的恶唑啉衍生物。

  DOI：

  10.1016/s0040-4020(01)92658-4

文献信息

• Multiple coordination modes of hemilabile 3-dimethylaminopropyl chalcogenolates in platinum(II) complexes: Synthesis, spectroscopy and structures
  作者：Sandip Dey、Vimal K. Jain、Ray J. Butcher

  DOI：10.1016/j.ica.2007.01.002

  日期：2007.5

  N-dimethylaminopropyl chalcogenolates with platinum(II) compounds have been carried out and complexes of the types [PtCl(ECH2CH2CH2NMe2)]2 (1) (E = S (1a) and Se (1b)), [Pt(ECH2CH2CH2NMe2)2]n (2) (E = S (2a) and Se (2b)), [(PtCl2)2(Me2NCH2CH2CH2E)2}]n (3), [PtX(SeCH2CH2CH2NMe2)]2 (4) (X = SePh (4a) and OAc (4b)) and [PtCl(ECH2CH2CH2NMe2)(PR3)]n (5) (E = S, Se, Te) have been isolated. These complexes have been

  摘要进行了N，N-二甲基氨基丙基硫属元素化物与铂（II）化合物的反应，并形成了[PtCl（ECH2CH2CH2NMe2）] 2（1）（E = S（1a）和Se（1b））型络合物，[ Pt（ECH2CH2CH2NMe2）2] n（2）（E = S（2a）和Se（2b）），[（PtCl2）2 （Me2NCH2CH2CH2E）2}] n（3），[PtX（SeCH2CH2CH2NMe2）] 2（4 ）（X = SePh（4a）和OAc（4b））和[PtCl（ECH2CH2CH2NMe2）（PR3）] n（5）（E = S，Se，Te）已分离。这些络合物已通过元素分析，IR，UV-Vis，NMR（1H，13C，31P，77Se，195Pt）光谱和FAB质谱数据进行了表征。[PtCl（SeCH2CH2CH2NMe2）] 2（1b）和[PtCl（SCH2CH2CH2NMe2）（PPr3）] 2（5a）
• Flavoring with dialkylamino-alkylene mercaptans and sulfides
  申请人：Givaudan Corporation

  公开号：US04285984A1

  公开（公告）日：1981-08-25

  Dialkylamino-alkylene mercaptans and sulfides, useful for preparing flavoring compositions and foodstuffs and tobaccos, and process for preparing said compositions, foodstuffs and tobaccos.

  Dialkylamino-alkylene mercaptans和sulfides，可用于制备调味料组合物、食品和烟草，以及制备所述组合物、食品和烟草的过程。
• Modified ion exchange resins and use thereof
  申请人：Mitsubishi Chemical Corporation

  公开号：US05589517A1

  公开（公告）日：1996-12-31

  A modified strongly acidic ion exchange resin of a sulfonic acid type is disclosed. Modification is conducted by ionically binding a particular N,N-di-substituted mercaptoalkylamine to a strongly acidic ion exchange resin of a sulfonic acid type. The N,N-di-substituted mercaptoalkylamine is specifically represented by the following formulae: ##STR1## wherein R.sup.1 represents hydrogen or a C.sub.1-6 alkyl group, R.sup.2 and R.sup.3 independently represent a C.sub.1-10 alkyl group, a and b denote 0-3, respectively, a+b denotes 2 or 3, and m denotes 4 or 5. The modified ion exchange resin makes an improved catalyst in the preparation of a bisphenol by the condensation reaction of a phenol with a ketone.

  本发明涉及一种改性的强酸性磺酸型离子交换树脂。改性是通过将特定的N，N-二取代巯基烷胺离子地结合到磺酸型强酸性离子交换树脂上进行的。N，N-二取代巯基烷胺特别表示为以下公式：##STR1## 其中R1表示氢或C1-6烷基，R2和R3分别独立地表示C1-10烷基，a和b分别表示0-3，a+b表示2或3，m表示4或5。改性离子交换树脂在苯酚与酮的缩合反应制备双酚时可作为改进的催化剂。
• METHOD OF COLOURING AND LIGHTENING KERATIN MATERIALS IN THE PRESENCE OF A REDUCING AGENT COMPRISING A FLUORESCENT DISULPHIDE DYE
  申请人：Daubresse Nicolas

  公开号：US20120177587A1

  公开（公告）日：2012-07-12

  The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.

  该发明涉及一种染料组合物，包括荧光二硫化物染料，以及一种使用该组合物进行具有减淡效果的角蛋白材料染色的方法。它还涉及新的荧光二硫化物染料及其在角蛋白材料减淡方面的应用。该组合物可使得得到一种特别持久的减淡效果。
• METHOD OF DYEING AND LIGHTENING KERATIN MATERIALS IN THE PRESENCE OF A REDUCING AGENT COMPRISING A FLUORESCENT DEISULPHIDE DYE
  申请人：L'OREAL

  公开号：US20140033450A1

  公开（公告）日：2014-02-06

  The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.

  本发明涉及一种染料组合物，其包括荧光二硫化物染料，并涉及一种使用该组合物进行具有减轻效果的角蛋白材料染色的方法。本发明还涉及新的荧光二硫化物染料及其在角蛋白材料减轻中的用途。该组合物可使得减轻效果尤为持久。