[ethyl 2-cyano-3-[(4-methylphenyl)amino]acrylatemesityl]bis(triphenylphosphino)nickel(II) | 863666-55-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [ethyl 2-cyano-3-[(4-methylphenyl)amino]acrylatemesityl]bis(triphenylphosphino)nickel(II)
• CAS: 863666-55-1
• 化学式: C₅₈H₅₄N₂NiO₂P₂
• 分子量: 931.716
• InChiKey: WEKGHKDJJBVPMY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-(bromomesityl)bis(triphenylphosphino)nickel(II) 、 ethyl 2-cyano-3-[(4-methylphenyl)amino]acrylate 在 sodium bis(trimethylsilyl)amide 作用下， 以 甲苯 为溶剂， 以58%的产率得到[ethyl 2-cyano-3-[(4-methylphenyl)amino]acrylatemesityl]bis(triphenylphosphino)nickel(II)
  参考文献：
  名称：

  3-Aminoiminoacrylate, 3-Aminoacrylate, and 3-Amidoiminomalonate Complexes as Catalysts for the Dimerization of Olefins

  摘要：

  Nickel(II)-aminoacrylate, -aminoiminoacrylate, and -amidoiminomalonate complexes 1-4 are suitable precursors together with appropriate cocatalysts for the catalytic dimerization of ethylene, propylene, and alpha-olefins with short chain lengths such as 1-hexene. Suitable ligands IV-VI, VIII, X, and XII generate nickel(II) compounds 1-4 active for these catalytic dimerizations. The influence of different substituents attached to the coordinating ligand backbone is tested in the catalytic reactions. Several novel monodentate and chelate nickel(II) precursor complexes 1 and 3 were isolated and also characterized by X-ray structure analysis.

  DOI：

  10.1021/om049075s