10,23:11,22-diepoxy-4b,8b,12b,16b,20b,24b,24d,24e-octamethyl-4b,8b,10,10a,11,12b,16b,20b,22,22a,23,24b,24d,24e-tetradecahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-k]tetracene | 1354700-37-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 10,23:11,22-diepoxy-4b,8b,12b,16b,20b,24b,24d,24e-octamethyl-4b,8b,10,10a,11,12b,16b,20b,22,22a,23,24b,24d,24e-tetradecahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-k]tetracene
• 英文别名: syn-bis-TBTQ diepoxide
• CAS: 1354700-37-0
• 化学式: C₅₈H₅₀O₂
• 分子量: 779.034
• InChiKey: SZZMPYKQFKGYQP-CJBMNHIUSA-N

反应信息

• 作为反应物：
  描述：

  10,23:11,22-diepoxy-4b,8b,12b,16b,20b,24b,24d,24e-octamethyl-4b,8b,10,10a,11,12b,16b,20b,22,22a,23,24b,24d,24e-tetradecahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-k]tetracene 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 0.33h， 以38%的产率得到2,3-diformyl-4b,8b,12b,12d-tetramethyl-4b,8b,12b,12d-tetrahydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene
  参考文献：
  名称：

  Single-wing Extended Tribenzotriquinacenes via Bowl-shaped Dehydrobenzene and Isobenzofuran Tribenzotriquinacene Derivatives

  摘要：

  Monoaryne and monoisobenzofuran analogues of a C-3v-symmetrical tribenzotriquinacene (TBTQ) were generated in situ and trapped with various dienes and dienophiles, respectively. In this way, a series of single-wing extended TBTQ derivatives bearing the bowl-shaped TBTQ unit in different topographical expositions have become accessible. This includes some novel tribenzotriquinacene "dimers", in which two TBTQ bowls are attached in syn- or anti-orientation at the terminal positions of rigid linker units. Several of these compounds have been characterized by both spectroscopy and X-ray structural analysis. The efficient access to the TBTQ "dimers" studies of novel container compounds and supramolecular architectures.

  DOI：

  10.1021/jo2022668
• 作为产物：
  描述：

  10,13-epoxy-4b,8b,14b,14d-tetramethyl-4b,8b,10,13,14b,14d-hexahydrobenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b]naphthalene 在 3,6-二-2-吡啶基-1,2,4,5-四嗪 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以61%的产率得到10,23:11,22-diepoxy-4b,8b,12b,16b,20b,24b,24d,24e-octamethyl-4b,8b,10,10a,11,12b,16b,20b,22,22a,23,24b,24d,24e-tetradecahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-k]tetracene
  参考文献：
  名称：

  Single-wing Extended Tribenzotriquinacenes via Bowl-shaped Dehydrobenzene and Isobenzofuran Tribenzotriquinacene Derivatives

  摘要：

  Monoaryne and monoisobenzofuran analogues of a C-3v-symmetrical tribenzotriquinacene (TBTQ) were generated in situ and trapped with various dienes and dienophiles, respectively. In this way, a series of single-wing extended TBTQ derivatives bearing the bowl-shaped TBTQ unit in different topographical expositions have become accessible. This includes some novel tribenzotriquinacene "dimers", in which two TBTQ bowls are attached in syn- or anti-orientation at the terminal positions of rigid linker units. Several of these compounds have been characterized by both spectroscopy and X-ray structural analysis. The efficient access to the TBTQ "dimers" studies of novel container compounds and supramolecular architectures.

  DOI：

  10.1021/jo2022668