2,4-Dinitrobenzol-sulfobromid | 2297-23-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-Dinitrobenzol-sulfobromid
• 英文别名: 2.4-Dinitro-benzolsulfonylbromid；2.4-Dinitro-benzolsulfonsaeurebromid；2,4-dinitrobenzenesulfonyl bromide
• CAS: 2297-23-6
• 化学式: C₆H₃BrN₂O₆S
• 分子量: 311.07
• InChiKey: CGJVJVBQENEISI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  134
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• METHOD FOR PRODUCING AMINO ACID DERIVATIVES
  申请人：API CORPORATION

  公开号：US20210403427A1

  公开（公告）日：2021-12-30

  The present invention aims to provide a method for producing a (2S,5R)-5-(protected oxyamino)-piperidine-2-carboxylic acid derivative at a low cost that can be performed under mild reaction conditions not requiring a facility at an extremely low temperature, is safer, can control the quality of the desired product with ease, and shows good workability in the site of production. A method for producing a compound represented by the formula (2): wherein PG 1 is an amino-protecting group, PG 2 is an amino-protecting group, PG 3 is a hydroxyl-protecting group, LG is a leaving group, and R is a hydrocarbon group having 1-8 carbon atoms and optionally having substituent(s), including a step of reacting a compound represented by the formula (1): wherein each symbol is as defined above, with a hydroxylamine derivative represented by the formula PG 2 NHOPG 3 wherein each symbol is as defined above, in the presence of a base in a solvent.

  本发明旨在提供一种低成本的方法，用于在温和反应条件下生产(2S,5R)-5-(保护氧氨基)-哌啶-2-羧酸衍生物，不需要极低温度设施，更安全，并且可以轻松控制所需产品的质量，在生产现场具有良好的可操作性。该方法包括以下步骤：与公式（1）所表示的化合物在溶剂中反应，其中PG1是氨基保护基，PG2是氨基保护基，PG3是羟基保护基，LG是离去基团，R是具有1-8个碳原子的烃基，并且可选地具有取代基，与公式PG2NHOPG3所表示的羟胺衍生物在碱的存在下反应。
• Water-dispersible energy curable heterocyclic group-containing polyesters
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0040002A1

  公开（公告）日：1981-11-18

  Water-dispersible radiation curable polyesters having backbone hydantoin groups and alpha-methylene groups, prepared e.g. from bis-glycidyl-hydantoin and itaconic acid. These polyesters are useful in the field of graphic arts.

  具有海因基团和α-亚甲基基团的水分散型辐射固化聚酯，例如由双缩水甘油海因和衣康酸制备而成。这些聚酯可用于制图领域。
• Method for coating ophthalmic devices
  申请人：SIGNET ARMORLITE, INC.

  公开号：EP0102847A1

  公开（公告）日：1984-03-14

  An ophthalmic lens and a method for providing a thin coating thereon is disclosed. The coatings render the surfaces of the devices resistant to abrasion and have an SEB abrasion resistance of at least 20 psi. They are optically clear, aberration-free, and provide essentially exactly an optical surface having the desired surface configuration. The coating compositions employed contain reactive ethylenically unsaturated groups and are applied to a mold face and partially reacted. The coated mold is then used to cast the ophthalmic device.

  本发明公开了一种眼科镜片及其薄涂层方法。镀膜使设备表面具有耐磨性，其 SEB 耐磨性至少为 20 psi。它们在光学上是透明的、无像差的，并能提供基本上完全符合所需表面构造的光学表面。采用的涂层组合物含有反应性乙烯不饱和基团，涂在模具表面并进行部分反应。然后用涂有涂层的模具浇铸眼科设备。
• Ultra-violet light curable compositions for abrasion resistant articles
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0168226A2

  公开（公告）日：1986-01-15

  Inherently highly abrasion-resistant cast articles are prepared by polymerizing a composition comprising (I) as a first component from 0 to 100 parts of urethane polyacrylic ester and (II) as a second component, correspondingly from 100 to 0 parts of a composition containing (A) 45 to 60% by weight of a polyacrylic ester having 4 to 10 acryloyloxy groups, (B) 20 to 55% by weight of a polymerization shrinkage modifier, and (C) 0 to 30% of a diluent monomer. A source of free-radicals may be added to the composition.

  固有高耐磨铸件是通过聚合一种组合物来制备的，该组合物包括：(I) 作为第一组分的 0 至 100 份聚氨酯聚丙烯酸酯；(II) 作为第二组分的 100 至 0 份组合物，该组合物相应地含有：(A) 45 至 60% （按重量计）具有 4 至 10 个丙烯酰氧基的聚丙烯酸酯；(B) 20 至 55% （按重量计）聚合收缩改性剂；(C) 0 至 30% 稀释剂单体。组合物中可加入自由基源。
• Abrasion resistant urethane coatings
  申请人：——

  公开号：US20010051229A1

  公开（公告）日：2001-12-13

  A radiation curable and abrasion resistant coating composition is provided comprising: (a) 70% to 98% by weight of an urethane-acrylate oligomer; (b) 2% to 30% of fine particles of a filler capable of imparting abrasion resistance having an average particle size in the range of 1-20 microns; (c) optionally a reactive diluent; and (d) optionally an synthetic resin. The coatings when applied to wood floorings impart superior abrasion resistance.

  提供了一种辐射固化耐磨涂料组合物，其成分包括：(a) 70% 至 98% （按重量计）的氨基甲酸乙酯-丙烯酸酯低聚物；(b) 2% 至 30% （按重量计）的可赋予耐磨性的填料细颗粒，其平均粒径在 1-20 微米范围内；(c) 可选的反应性稀释剂；以及 (d) 可选的合成树脂。这种涂料涂在木地板上，具有极佳的耐磨性。