4-allyl-1,2-dicyanobenzene | 1363377-26-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-allyl-1,2-dicyanobenzene
• 英文别名: 4-allylphthalonitrile；4-Prop-2-enylbenzene-1,2-dicarbonitrile
• CAS: 1363377-26-7
• 化学式: C₁₁H₈N₂
• 分子量: 168.198
• InChiKey: UAGFWHDBWONONX-UHFFFAOYSA-N

物化性质

• 沸点：
  338.8±37.0 °C(Predicted)
• 密度：
  1.08±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  、 4-碘酞腈 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以94%的产率得到4-allyl-1,2-dicyanobenzene
  参考文献：
  名称：

  JP5650959

  摘要：

  公开号：

文献信息

• Photosubstitution of Dicyanoarenes by Hypervalent Allylsilicon Reagents via Photoinduced Electron Transfer
  作者：Daisuke Matsuoka、Yutaka Nishigaichi

  DOI：10.1246/cl.131132

  日期：2014.4.5

  Photosubstitution of dicyanoarenes with hypervalent allylsilicon reagents in the presence of anthracene efficiently proceeded to afford the allyl-substituted product in moderate to good yields. The efficiency for the present photoreaction was much higher than that for the tetracoordinate allylsilanes, because hypervalent allylsilicon reagents possess lower oxidation potential than the tetracoordinate ones, which resulted in more efficient photoinduced electron-transfer process.

  在蒽的存在下，二氰基烯烃与高价烯丙基硅试剂的光取代反应可以有效地进行，从而得到烯丙基取代的产物，收率为中等到良好。与四配位烯丙基硅烷相比，本光反应的效率要高得多，这是因为高价烯丙基硅试剂的氧化电位比四配位烯丙基硅试剂的氧化电位低，因此光诱导电子转移过程的效率更高。
• Allyl-transfer Reaction from Photoexcited Hypervalent Allylsilicon Reagent toward Dicyanobenzenes
  作者：Daisuke Matsuoka、Yutaka Nishigaichi

  DOI：10.1246/cl.140940

  日期：2015.2.5

  Photoreaction between dicyanobenzenes and a hypervalent allylsilicon reagent using 2,3-dihydroxynaphthalene as a ligand on silicon efficiently proceeded to afford allyl-substituted benzonitriles in moderate to good yields. The present photoreaction was found to occur based on the excitation of the hypervalent allylsilicon reagent.

  使用 2,3-二羟基萘作为硅上的配体，二氰基苯和高价烯丙基硅试剂之间的光反应有效地进行，以中等至良好的产率提供烯丙基取代的苯甲腈。发现本发明的光反应是基于高价烯丙基硅试剂的激发而发生的。
• JP5651037
  申请人：——

  公开号：——

  公开（公告）日：——
• JP2011162575A
  申请人：——

  公开号：JP2011162575A

  公开（公告）日：2011-08-25
• PHTHALOCYANINE/ POLYMER NANOCOMPOSITE INK FOR OPTOELECTONICS
  申请人：Zongxiang Xu

  公开号：US20130217811A1

  公开（公告）日：2013-08-22

  Aspects describe phthalocyanine (Pc) molecules with peripheral modifications of its core (e.g., alkyl substituents) so that the Pc can self assemble, for example under vacuum sublimation, and form nanocrystals of a size on the order of nanometers. The Pc nanocrystals can be prepared, for example, by a simple vapor deposition method. Further aspects describe a polymer composite ink based Pc nanocrystals in a polymer matrix, which can be formed, for example, under a solution process approach. For example, the polymer matrix can be a different p-type conjugated polymer from the Pc nanocrystals, which are inherently p-type semi-conductors. This can increase the film formation ability and charge transport properties of the polymer composite ink. The polymer composite ink can be utilized, for example, in the fabrication of optoelectronic devices, such as photovoltaic devices and/or thin film transistors. The optoelectronic devices can exhibit high power conversion efficiency (PCE), for example 6-7 percent.