| 154649-07-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 154649-07-7
• 化学式: C₂H₆O*C₂₄H₂₃Cl₃NO₂P₂Re
• 分子量: 758.035
• InChiKey: ABHIVPHXUUSSGA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetraphenylarsonium oxotetrachlororhenate(V) 、 N,N-双(二苯磷)胺 以 氯仿 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Reactivity of the rhenium(V)–oxo complex [AsPh₄][ReOCl₄] toward bis(diphenylphosphino)amine NH(PPh₂)₂. Synthesis and crystal structures

  摘要：

  The complexes [ReCl3(H2O){NH(OPPh(2))PPh(2)-P,O}] 1. [ReCl4{NH(OPPh(2))PPh(2)-P,O}] 3 and [AsPh(4)][ReCl4{N(OPPh(2))PPh(2)-P,O}] 4 were obtained by treatment of [AsPh(4)][ReOCl4] with NH(PPh(2))(2) under different experimental conditions. Their structures were determined by X-ray crystallography. In all complexes the co-ordination is nearly octahedral where a molecule of the ligand binds to rhenium through a phosphorus and oxygen. The Re-O distances. which range from 2.054(3) to 2.071(6) Angstrom indicate the presence of neutral or partially negatively-charged oxygens. The Re-Cl bond distances trans to oxygen are strongly related to the oxygen charge and hybridization.

  DOI：

  10.1039/dt9940000339