nitromalondialdehyde bis-[(2-N-tosylamino)anile] | 478844-55-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: nitromalondialdehyde bis-[(2-N-tosylamino)anile]
• 英文别名: bis[(N-tosylamino)anil] of nitromalonaldehyde；4-methyl-N-[2-[[3-[2-[(4-methylphenyl)sulfonylamino]phenyl]imino-2-nitroprop-1-enyl]amino]phenyl]benzenesulfonamide
• CAS: 478844-55-2
• 化学式: C₂₉H₂₇N₅O₆S₂
• 分子量: 605.695
• InChiKey: PVWJZOYQNIRAQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  42
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  179
• 氢给体数：
  3
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  nitromalondialdehyde bis-[(2-N-tosylamino)anile] 、 cobalt(II) acetate 在 KOH 作用下， 以 1,4-二氧六环 、 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Trinuclear metal chelates of β-aminovinylimines

  摘要：

  The chemical and electrochemical synthesis of trinuclear metal chelates of Cu(II), Ni(II), Co(II), Zn(II), and Cd(II) with a new tetradentate ligand system bis-[(2-oxy, -mercapto, N-tosylamino)anyls] of nitro- and phenylmalondialdehyde was carried out. Magnetic and EPR-spectral data showed that the spin-spin exchange interactions of the antiferromagnetic type between copper ions possess inner- and intermolecular character and depend on the composition of the coordination unit, the nature of the substituent in the malondialdehyde fragment, and the synthetic technique applied. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01079-3

文献信息

• Trinuclear Metal Chelates of β-Aminovinylimines
  作者：A. S. Burlov、L. I. Kuznetsova、A. I. Uraev、V. P. Kurbatov'†、G. I. Bondarenko、I. S. Vasil'chenko、A. D. Garnovskii

  DOI：10.1023/b:rugc.0000007639.42616.88

  日期：2003.8

  The chemical and electrochemical syntheses of Cu(II), Ni(II), Co(II), Zn(II), and Cd(II) trinuclear metal chelates with a new tetradentate ligand system including bis-[(2-hydroxy-, -mercapto-, and -N-tosylamino)anils] of nitro- and phenylmalonaldehyde were performed. Temperature dependences of magnetic and ESR spectral properties of the complexes were studied to show that the antiferromagnetic spin-spin exchange interactions between copper(II) ions are intra- and intermolecular in nature and depend on the composition and structure of the coordination units, steric effects, nature of the substituent in the malonaldehyde moiety of the ligand, as well as on the method of synthesis of the complex compounds.