| 1233348-31-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1233348-31-6
• 化学式: C₂₉H₃₄N₂O₃Si
• 分子量: 486.686
• InChiKey: VROAKUXMSOTNIN-NPIYKFRDSA-N

反应信息

• 作为反应物：
  描述：

  在 四氟硼酸-二乙醚络合物 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  On the [3 + 2] Annulation of Cyclic Allylsilanes with N-Phenyltriazolinedione: An Enantio- and Diastereoselective Synthesis of cis-1,3-Diaminocyclitols

  摘要：

  Improved conditions were found to trigger [3 + 2] annulation of cyclic allylsilanes with N-phenyltriazolinedione (PTAD); the products from this reaction were readily tailored into cis-1,3-diaminocyclitols in highly enantioenriched form with full stereochemical control of up to four contiguous stereogenic centers.

  DOI：

  10.1021/jo100724w
• 作为产物：
  描述：

  2-[(2-methoxyphenyl)dimethylsilanyl]cyclohexane-1,3-diamine 、 苯甲酰氯 在 吡啶 、 4-二甲氨基吡啶 作用下， 以 二氯甲烷 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  On the [3 + 2] Annulation of Cyclic Allylsilanes with N-Phenyltriazolinedione: An Enantio- and Diastereoselective Synthesis of cis-1,3-Diaminocyclitols

  摘要：

  Improved conditions were found to trigger [3 + 2] annulation of cyclic allylsilanes with N-phenyltriazolinedione (PTAD); the products from this reaction were readily tailored into cis-1,3-diaminocyclitols in highly enantioenriched form with full stereochemical control of up to four contiguous stereogenic centers.

  DOI：

  10.1021/jo100724w