di-chloro-[1-methyl-2-(naphthyl-β-azo)-imidazole]cadmium(II) | 929644-79-1

• 英文名称: di-chloro-[1-methyl-2-(naphthyl-β-azo)-imidazole]cadmium(II)
• 英文别名: [Cd(β-NaiMe)Cl2]
• CAS: 929644-79-1
• 化学式: C₁₄H₁₂CdCl₂N₄
• 分子量: 419.592
• InChiKey: WPOOXHSMFZCQLC-ISQLRVRESA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-methyl-2-(naphthyl-β-azo)-imidazole 、 cadmium(II) chloride 以 甲醇 为溶剂， 生成 di-chloro-[1-methyl-2-(naphthyl-β-azo)-imidazole]cadmium(II)
  参考文献：
  名称：

  Synthesis, spectral characterization and photoluminescence properties of cadmium(II) complexes of N-[(2-pyridyl)methyliden]-α (or β)-aminonaphthalene (α- or β-NaiPy) and comparison with the complexes of 1-alkyl-2-(naphthyl-α (or β)-azo)imidazole. Single crystal X-ray structure of [Cd(β-NaiPy)2(ONO2)2]

  摘要：

  Cadmium(II) complexes of N-[(2-pyridyl)methyliden]-alpha (or beta)-aminonaphthalene (alpha or beta-NaiPy) and 1-alkyl-2-(naphthyl-alpha (or beta)-azo)imidazoles (alpha- or beta-NaiR) using Cl-, ClO4- and NO3- as anions are spectroscopically characterized. Molar conductance data in nitromethane show that the chloro and nitrite compounds are non-conducting, while the perchlorate complexes are 1:2 electrolytes. The single crystal X-ray structure of [Cd(N-{(2-pyridyl)methyliden}-beta-aminonaphthalene)(2)(ONO2)(2)] has been determined. The luminescence properties of Cd(II) complexes of alpha/beta-NaiPy are studied and they exhibit ligand centered pi-pi* emissions. Naphthylazoimidazoles and their cadmium complexes are non-fluorescent. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.08.014