| 88242-52-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 88242-52-8
• 化学式: C₁₈H₂₄N₂NiO₂S₄
• 分子量: 487.355
• InChiKey: WTTPKYXIOWPIHD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 bis(O-isopropylxanthato)nickel(II) 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Reactions of bis(isopropylxanthato)nickel(II) with nitrogen-donor ligands—II

  摘要：

  New complexes of bivalent nickel with isopropylxanthates and nitrogen-donor ligands of composition [Ni(Pr(i)xa)(2)(L)], [Ni(Pr(i)xa)(2)(L(1))(2)], [Ni(L(2))(2)](Pr(i)xa)(2), and [Ni(L(3))(3)] (Pr(i)xa)(2) have been synthesized, where Pr(i)xa = i-C3H7OCS2-, L = 1,2-diaminopropane (1,2-pn), N,N,N',N'-tetramethylethylenediamine (tmen) or 4,4'-bipyridine (4,4'-bipy), L(1) = pyridine (py), L(2) = diethylenetriamine (dien) and L(3) = ethylenediamine (en), 1,2-diaminopropane or 1,10-phenanthroline (phen). The compounds have been characterized by elemental analysis, IR and UV-vis spectroscopy, magnetochemical measurements, molar conductivity and thermal analysis. The compounds containing the complex cation have been one-electron irreversibly oxidized using cyclic voltammetry. The crystal and molecular structures of [Ni(Pr(i)xa)(2)(tmen)] and [Ni(phen)(3)](Pr(i)xa)(2) have been elucidated.

  DOI：

  10.1016/0277-5387(95)00159-p