[Cu2(3,5-pyrazoledicarboxylic acid(2-))2]4,4'-dipyridyl-N,N'-dioxidefc | 627089-39-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu2(3,5-pyrazoledicarboxylic acid(2-))2]4,4'-dipyridyl-N,N'-dioxidefc
• CAS: 627089-39-8
• 化学式: C₁₀H₄Cu₂N₄O₈*C₁₀H₈N₂O₂
• 分子量: 623.441
• InChiKey: PIWPNZXTVFEVAL-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 4,4-二吡啶基N,N-二氧化水合物 、 monopotassium 3,5-pyrazoledicarboxylate 以 甲醇 、 水 为溶剂， 生成 [Cu2(3,5-pyrazoledicarboxylic acid(2-))2]4,4'-dipyridyl-N,N'-dioxidefc
  参考文献：
  名称：

  Syntheses, structures and properties of two one-dimensional chain complexes: [Mn(Hpdc)(H2O)2]n and [Cu2(Hpdc)2][4,4′-dpdo] (Hpdc=3,5-pyrazoledicarboxylic acid group, dpdo=4,4′-dipyridyl-N,N′-dioxide hydrate)

  摘要：

  Two one-dimensional chain complexes: [Mn(Hpdc)(H2O)(2)](n) (1) and [Cu-2(Hpdc)(2)][4,4'-dpdo] (2) have been synthesized from hydrothermal solutions at 150 degreesC. Both structures are mainly constructed by a single multifunctional ligand, monopotassium 3,5-pyrazoledicarboxylate (KH(2)pdc). All metal atoms are six-coordinated in 1, two kinds of carboxylic bridges are found between manganese atoms to form a one-dimensional chain and further construct three-dimensional structure by hydrogen bonds. In 2, all copper atoms are five-coordinated, Cu1 and Cu1A are linked by the nitrogen atoms in the pyrazole ring to form a dimmer and two-dimensional structure is formed by weak coordination bonds and hydrogen bonds. Susceptibility data of I and 2 show antiferromagnetic coupling interactions. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00174-6