1-(4-Trifluoromethyl-phenyl)-2-propyl-propenone | 363565-01-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-Trifluoromethyl-phenyl)-2-propyl-propenone
• 英文别名: 2-Methylidene-1-[4-(trifluoromethyl)phenyl]pentan-1-one
• CAS: 363565-01-9
• 化学式: C₁₃H₁₃F₃O
• 分子量: 242.241
• InChiKey: QTTJKTUASKPZHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Arthropodicidal carboxanilides
  申请人：——

  公开号：US20030139397A1

  公开（公告）日：2003-07-24

  Compounds of Formula (I), and their N-oxides and agriculturally suitable salts, are disclosed which are useful as arthropodicides wherein A is H; E is H or C 1 -C 3 alkyl; or A and E can be taken together to form —CH 2 —, —CH 2 CH 2 —, —O—, —S—, —S(O)—, —S(O) 2 —, —NR 8 —, —OCH 2 —, —SCH 2 —, —N(R 8 )CH 2 —, substituted —CH 2 — and substituted —CH 2 CH 2 —, the substituents independently selected from 1-2 halogen and 1-2 methyl; W is N or CR 4 ;X is CR 5 R 6 , O, S, NR 7 or a direct bond, provided that when W is N, then X is other than a direct bond; Y is H, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 1 -C 3 alkylsulfonyl, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkylalkyl, NR 9 R 10 , N═CR 11 R 12 , OR 7 , COR 13 , CO 2 R 14 or C 1 -C 6 alkyl substituted by at least one group selected from halogen, C 1 -C 3 alkoxy, CN, NO 2 , S(O) 1 R 15 , COR 13 , CO 2 R 14 and optionally substituted phenyl; Z is O or S; and R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , G, n and r are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (I) and a method for controlling arthropods which involves contacting the arthropods or their environment with an effective amount of a compound of Formula (I).

  揭示了式(I)的化合物及其N-氧化物和适用于农业的盐，其可用作节肢动物杀虫剂，其中A为H；E为H或C1-C3烷基；或A和E可以结合形成-CH2-，- -，-O-，-S-，-S（O）-，-S（O）2-，-NR8-，-O -，-S -，-N（R8） -，取代的- -和取代的- -，取代基独立地选择自1-2卤素和1-2甲基；W为N或CR4；X为CR5R6，O，S，NR7或直接键，但当W为N时，则X不是直接键；Y为H，C1-C6烷基，C2-C6烯基，C2-C6炔基，C1-C3烷基磺酰基，C3-C6环烷基，C3-C6环烷基烷基，NR9R10，N═CR11R12，OR7，COR13，CO2R14或C1-C6烷基，该烷基被至少选择一个从卤素，C1-C3烷氧基，CN，NO2，S（O）1R15，COR13，CO2R14和可选择取代的苯基的基团取代；Z为O或S；R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12、R13、R14、R15、G、n和r如所述的披露。还揭示了含有式(I)化合物的组合物以及控制节肢动物的方法，该方法涉及使用式(I)化合物的有效量接触节肢动物或其环境。
• ARTHROPODICIDAL CARBOXANILIDES
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1268408A1

  公开（公告）日：2003-01-02
• US6818641B2
  申请人：——

  公开号：US6818641B2

  公开（公告）日：2004-11-16
• [EN] ARTHROPODICIDAL CARBOXANILIDES<br/>[FR] CARBOXANILIDES ARTHROPODICIDES
  申请人：DU PONT

  公开号：WO2001072696A1

  公开（公告）日：2001-10-04

  Compounds of Formula (I), and their N-oxides and agriculturally suitable salts, are disclosed which are useful as arthropodicides wherein A is H; E is H or C1-C3 alkyl; or A and E can be taken together to form -CH2-, -CH2CH2-, -O-, -S-, -S(O)-, -S(O)2-, -NR8-, -OCH¿2?-, -SCH2-, -N(R?8)CH¿2-, substituted -CH2- and substituted -CH2CH2-, the substituents independently selected from 1-2 halogen and 1-2 methyl; W is N or CR4;X is CR5R6, O, S, NR7 or a direct bond, provided that when W is N, then X is other than a direct bond; Y is H, C¿1?-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C1-C3 alkylsulfonyl, C3-C6 cycloalkyl, C3-C6 cycloalkylalkyl, NR?9R10, N=CR11R12, OR7, COR13, CO¿2R14 or C1-C6 alkyl substituted by at least one group selected from halogen, C1-C3 alkoxy, CN, NO2, S(O)rR?15, COR13, CO¿2R14 and optionally substituted phenyl; Z is O or S; and R?2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15¿, G, n and r are as defined in the disclosure.Also disclosed are compositions containing the compounds of Formula (I) and a method for controlling arthropods which involves contacting the arthropods or their environment with an effective amount of a compound of Formula (I).