1,2-Epoxy-3-(2',4',6'-trimethylphenoxy)-propan | 51673-11-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-Epoxy-3-(2',4',6'-trimethylphenoxy)-propan
• 英文别名: 2,4,6-Trimethylphenylglycidaether；(2,4,6-trimethyl-phenoxymethyl)-oxirane；2',4',6'-trimethyl-phenyl glycidyl ether；2-[(2,4,6-Trimethylphenoxy)methyl]oxirane
• CAS: 51673-11-1
• 化学式: C₁₂H₁₆O₂
• 分子量: 192.258
• InChiKey: VSLBTETWJICFKD-UHFFFAOYSA-N

物化性质

• 沸点：
  284.6±35.0 °C(Predicted)
• 密度：
  1.053±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-Epoxy-3-(2',4',6'-trimethylphenoxy)-propan 、 N-benzyl-N'-[2-butyl-3-oxo-4-chloro-pyridaz-5-yl]-ethylenediamine 以 1,4-二氧六环 、 乙醇 、 甲烷 为溶剂， 以68%的产率得到N-[3-(2',4',6'-trimethylphenoxy)-2-hydroxy-propyl]-N'-[2-butyl-3-oxo-4-chloro-pyridaz-5-yl]-ethylenediamine
  参考文献：
  名称：

  N-phenoxypropanol-N'-pyridazinyl ethylendiamines as .beta.-receptor

  摘要：

  基本上，公式为##STR1##的取代吡啶嗪化合物，其中R.sup.1、R.sup.2和R.sup.3独立地表示氢、卤素、羟基、硝基、三氟甲基、烷基、烷氧基烷基、烯基、炔基、环烷基、环烯基、苯基、烷氧基、羟基烷氧基、烷氧基-烷氧基、烯氧基、炔氧基、环烷氧基、苯基氧基、醇酰基、醇酰氨基和--NH--CO--R.sup.9，其中R.sup.9代表吗啉基、哌啶基或1-吡咯啉基，或者是一个可选择取代的脲基团，R.sup.4代表氢或低碳烷基，W代表氢、氯或溴；以及它们的酸盐，单独使用或在药物配方中用于治疗心脏疾病、循环疾病和高血压。还提供了几种制备基本取代吡啶嗪的方法。

  公开号：

  US04532239A1

文献信息

• Polymer electrolyte and method for producing the same
  申请人：——

  公开号：US20010041279A1

  公开（公告）日：2001-11-15

  Provided is a polymer electrolyte containing a block copolymer comprising one or more blocks having sulfonic acid groups and one or more blocks having substantially no sulfonic acid group, and at least one block among all blocks is a block having aromatic rings in the main chain thereof, and a method for producing the same. The polymer electrolyte is suitable for a proton conductive film of a fuel cell due to excellent water resistance and heat resistance, and high proton conductivity.

  提供的是一种聚合物电解质，包含一种嵌段共聚物，其中包括一个或多个具有磺酸基团的块和一个或多个几乎没有磺酸基团的块，而所有块中至少有一个块具有其主链中的芳香环，以及其制备方法。由于具有优异的耐水性、耐热性和高质子传导性，该聚合物电解质适用于燃料电池的质子传导膜。
• EPOXY RESIN COMPOSITION FOR PREPREG, PREPREG, AND MULTILAYERED PRINTED WIRING BOARD
  申请人：MATSUSHITA ELECTRIC WORKS, LTD.

  公开号：EP1818350A1

  公开（公告）日：2007-08-15

  Problems: To provide an epoxy resin composition for prepreg used in manufacturing a printed wiring board, particularly a multilayered printed wiring board, which does not generate toxic substance on combustion and excellent in ignition resistance, solder heat resistance after moisture absorption and high temperature rigidity, prepregs and multilayered printed wiring boards. Means for solving problems: A phosphorous compound comprising 1.8 or more but less than 3 phenolic hydroxyl groups on an average and 0.8 or more phosphorous atom on an average within a molecule is reacted in advance with a particular bifunctional epoxy resin (selected from biphenyl, naphthalene, dicylcopentadiene or other types) in a ratio of epoxy equivalent to phenolic hydroxyl equivalent to be 1.2 or more but less than 3 to 1 to yield a preliminarily reacted epoxy resin, of which 20% by mass to 55% by mass against the whole epoxy resin composition is formulated together with a multifunctional epoxy resin having 2.8 or more epoxy groups on an average within a molecule, a curing agent comprising dicyandiamide and/or multifunctional phenolic compound and an inorganic filler with thermal decomposition temperature of 400°C or above, yielding an epoxy resin composition which is used to prepare prepregs used in manufacturing a printed wiring board.

  问题提供一种用于制造印制电路板，特别是多层印制电路板的预浸料的环氧树脂组合物，该组合物在燃烧时不会产生有毒物质，并且在耐燃性、吸湿后的焊接耐热性和高温刚性、预浸料和多层印制电路板方面具有优异的性能。 解决问题的方法：将分子中平均含有 1.8 个或 1.8 个以上但少于 3 个酚羟基和 0.8 个或 0.8 个以上磷原子的磷化合物与特定的双官能环氧树脂（选自联苯、萘、双环戊二烯或其他类型）预先进行反应，环氧当量与酚羟基当量之比为 1.2 或更多，但小于 3 比 1，以得到初步反应的环氧树脂，其中占整个环氧树脂组合物 20% 至 55% 质量的环氧树脂组合物与分子内平均具有 2.8 或更多环氧基团的多功能环氧树脂、由双氰胺和/或多功能酚类化合物组成的固化剂和热分解温度为 400°C 或以上的无机填料配制在一起，得到用于制备印刷线路板预浸料的环氧树脂组合物。
• Polymer electrolyte
  申请人：Sumitomo Chemical Company Limited

  公开号：EP2461413A1

  公开（公告）日：2012-06-06

  Provided is a polymer electrolyte containing a block copolymer comprising one or more blocks having sulfonic acid groups and one or more blocks having substantially no sulfonic acid group, and at least one block among all blocks is a block having aromatic rings in the main chain thereof, and a method for producing the same. The polymer electrolyte is suitable for a proton conductive film of a fuel cell due to excellent water resistance and heat resistance, and high proton conductivity.

  本发明提供了一种聚合物电解质，它含有一种嵌段共聚物，该嵌段共聚物由一个或多个具有磺酸基团的嵌段和一个或多个基本上没有磺酸基团的嵌段组成，所有嵌段中至少有一个嵌段是主链上具有芳香环的嵌段，还提供了生产这种聚合物电解质的方法。该聚合物电解质具有优异的耐水性、耐热性和高质子传导性，适用于燃料电池的质子传导膜。
• Optical unit using plastic lenses
  申请人：Suzuki Fumiyuki

  公开号：US20060046065A1

  公开（公告）日：2006-03-02

  The present invention provides an optical unit for high-resolution applications all lenses in which are made of plastics. The optical unit includes lens ( 1 ) and ( 2 ). The lens ( 1 ) is a plastic lens having an Abbe number of 45-60. The lens ( 2 ) is a lens injection molded from a polycarbonate material comprising a structure derived from spirobiindan and having a glass transition temperature of 120-150° C.

  本发明提供了一种用于高分辨率应用的光学装置，其所有透镜均由塑料制成。光学单元包括透镜 ( 1 )和( 2 ).透镜 ( 1 ) 是一个阿贝数为 45-60 的塑料透镜。透镜 ( 2 )是由聚碳酸酯材料注塑而成的镜片，这种材料的结构来源于螺纹茚满，玻璃化温度为 120-150 摄氏度。
• RAABE, T.;BOHN, H.;MARTORANA, R. A.;NITZ, R. -E.
  作者：RAABE, T.、BOHN, H.、MARTORANA, R. A.、NITZ, R. -E.

  DOI：——

  日期：——