(E)-N-(1-chloronaphthalen-2-yl)-2-(hydroxyimino)acetamide | 1549704-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (E)-N-(1-chloronaphthalen-2-yl)-2-(hydroxyimino)acetamide
• CAS: 1549704-73-5
• 化学式: C₁₂H₉ClN₂O₂
• 分子量: 248.669
• InChiKey: YMDBRJBRPRZSCX-VGOFMYFVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.89
• 重原子数：
  17.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.69
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  (E)-N-(1-chloronaphthalen-2-yl)-2-(hydroxyimino)acetamide 在 硫酸 、 四氯化钛 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 生成 9-chloro-1H-benzo[f]indol-2(3H)-one
  参考文献：
  名称：

  Synthesis of a thiophene-fused isoindigo derivative: a potential building block for organic semiconductors

  摘要：

  Thiophene-fused isoindigo (TII) was synthesized from thieno[2,3-flindol-6(7H)-one in a one-pot reaction, in which the alkylation, oxidation and condensation were finished in one step. It exhibits better intramolecular charge transfer properties and higher reductive potential compared with isoindigo(II), as evidenced by its optical and electrochemical properties, which shows that it might be used as a building block for n-type or ambipolar OFET materials. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.12.076
• 作为产物：
  描述：

  2-萘胺 在 盐酸 、 N-氯代丁二酰亚胺 、 盐酸羟胺 、 sodium sulfate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 1.0h， 生成 (E)-N-(1-chloronaphthalen-2-yl)-2-(hydroxyimino)acetamide
  参考文献：
  名称：

  Synthesis of a thiophene-fused isoindigo derivative: a potential building block for organic semiconductors

  摘要：

  Thiophene-fused isoindigo (TII) was synthesized from thieno[2,3-flindol-6(7H)-one in a one-pot reaction, in which the alkylation, oxidation and condensation were finished in one step. It exhibits better intramolecular charge transfer properties and higher reductive potential compared with isoindigo(II), as evidenced by its optical and electrochemical properties, which shows that it might be used as a building block for n-type or ambipolar OFET materials. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.12.076