(4-Methylphenyl)-bis[4-(trifluoromethyl)phenyl]phosphane | 1289464-07-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Methylphenyl)-bis[4-(trifluoromethyl)phenyl]phosphane
• CAS: 1289464-07-8
• 化学式: C₂₁H₁₅F₆P
• 分子量: 412.314
• InChiKey: FCDIIGKZXWAKPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• N-(PHOSPHINOALKYL)-N-(THIOALKYL)AMINE DERIVATIVE, METHOD FOR PRODUCING SAME, AND METAL COMPLEX THEREOF
  申请人：TAKASAGO INTERNATIONAL CORPORATION

  公开号：US20170233418A1

  公开（公告）日：2017-08-17

  The purpose of the present invention is to provide: a ligand that is useful in a catalytic organic synthetic reaction; a method for producing said ligand; and a metal complex that is useful as a catalyst in an organic synthetic reaction. The present invention provides a compound represented by general formula (1 A ), a method for producing said compound, and a metal complex including said compound as a ligand. (In the formula, H, N, P, S, L, R 1 , R 2 , R 3 , Q 1 , and Q 2 have the meaning as defined in the Description.)

  本发明的目的是提供：在催化有机合成反应中有用的配体；制备所述配体的方法；以及在有机合成反应中作为催化剂有用的金属配合物。本发明提供了由通式（1A）表示的化合物，制备所述化合物的方法，以及包括所述化合物作为配体的金属配合物。（在该式中，H、N、P、S、L、R1、R2、R3、Q1和Q2的含义如描述中所定义。）
• [EN] TRIPHENYLPHOSPHINE DERIVATIVES<br/>[FR] DÉRIVÉS DE TRIPHÉNYLPHOSPHINE
  申请人：UNIV BARCELONA AUTONOMA

  公开号：WO2011045417A1

  公开（公告）日：2011-04-21

  The present invention relates to a triphenylphosphine of Formula (I) wherein M is a proton or a monovalent or divalent cation, n is an integer selected from 1 and 2, p takes a value selected from 1/2, 1 and 2, R1 is selected from H, C1-C18 alkyl, CF3 and SO3-, R11, R12 and R13 are independently selected from H and C1-C18 alkyl, with the proviso that if R1 is SO3-, then the product of n and p is equal to 2, R2, R3 and R5 are independently selected from H and C1-C18 alkyl, R4 is H, R6-R10 are independently selected from H, C1-C18 alkyl and CF3, at least one of R6-R10 being CF3; if R1 is not SO3-, then the product of n and p is equal to 1, R1-R10 are independently selected from H, C1-C18 is alkyl and CF3, at least one of the groups R1 -R10 being CF3; the present invention also is directed to a process for obtaining a triphenyl phosphine of Formula (I) and its use as ligand in the catalysis field and other several applications.

  本发明涉及一种三苯基膦化合物，其化学式为（I），其中M是质子或一价或二价阳离子，n是选自1和2的整数，p取值为1/2、1或2，R1选自H、C1-C18烷基、CF3和SO3-，R11、R12和R13独立地选自H和C1-C18烷基，但如果R1为SO3-，则n和p的乘积等于2，R2、R3和R5独立地选自H和C1-C18烷基，R4为H，R6-R10独立地选自H、C1-C18烷基和 ，其中至少一个为 ；如果R1不是SO3-，则n和p的乘积等于1，R1-R10独立地选自H、C1-C18烷基和 ，其中至少一个为 ；本发明还涉及一种制备化合物（I）的方法，以及其作为催化领域和其他几种应用中的配体。
• COMPOSITION AND POLYMER
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP2735581B1

  公开（公告）日：2021-07-14
• PRODUCTION METHOD OF COPOLYMER OF ALLYL MONOMER CONTAINING POLAR GROUP
  申请人：Nozaki Kyoko

  公开号：US20120116036A1

  公开（公告）日：2012-05-10

  The present invention relates to a method for producing a high-molecular-weight copolymer of polar group-containing allyl monomers including monomer units represented by formulae (3) and (4) (in the formulae, R 1 represents a hydrogen atom (H) or hydrocarbon group having 1 to 6 carbon atoms; R 2 represents —OH, —OCOR 3 (R 3 represents hydrocarbon group having 1 to 5 carbon atoms), —N(R 4 ) 2 (R 4 represents a hydrogen atom or hydrocarbon group having 1 to 5 carbon atoms); and n and m are a value representing the molar ratio of each of the monomer units), which has few branches and unsaturated group at the molecular end, by copolymerizing olefin and an allyl compound using a metal complex of group 10 elements in the periodic system represented by formula (I) as a catalyst.
• METHOD FOR PRODUCING POLAR GROUP-CONTAINING OLEFIN COPOLYMERS
  申请人：Okumura Yoshikuni

  公开号：US20130165607A1

  公开（公告）日：2013-06-27

  The present invention relates to a method of producing a polymer in the method for producing a copolymer of olefin and a polar group-containing monomer represented by formula (1): C(R 1 ) 2 ═C(R 1 )(C(R 1 ) 2 ) n R 2 (1) (in the formula, the symbols have the same meanings as described in the description), the method comprising using a complex of a metal in Group 10 of the periodic table as a catalyst; and supplying a catalyst solution separated from a polymer after the polymerization reaction to a polymerization reaction system to recycle and re-use the catalyst. The production method of the present invention can dramatically reduce the catalyst cost.