4,5-diphenyl-3,6-dihydrodiselenin | 1258522-84-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4,5-diphenyl-3,6-dihydrodiselenin
• CAS: 1258522-84-7
• 化学式: C₁₆H₁₄Se₂
• 分子量: 364.207
• InChiKey: WKOLWCCLYMJMJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.77
• 重原子数：
  18.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  4,5-diphenyl-3,6-dihydrodiselenin 在 selenium 作用下， 以 邻二氯苯 、 三氯苯 为溶剂， 反应 1.5h， 生成 2,5-dihydro-3,4-diphenylselenophene
  参考文献：
  名称：

  Quest for diatomic selenium

  摘要：

  Metallocene pentaselenides and elemental selenium were employed in an effort to generate diatomic selenium (Se2) under thermal conditions. Trapping experiments were carried out with six dienes. A successful formation of a diselenium adduct was observed in the case of 5,6-dimethylene-cyclohexa-1,3-diene (1a). The other dienes produced the corresponding dihydroselenophenes. The in-depth study of the limitations of our method to generate Se2 is described; a plausible mechanism rationalizing the observed results is proposed.

  DOI：

  10.1080/17415993.2010.513440
• 作为产物：
  描述：

  (Z)-1,4-diselenocyanato-2,3-diphenylbut-2-ene 在 sodium methylate 作用下， 以 甲醇 、 苯 为溶剂， 反应 3.0h， 以38%的产率得到4,5-diphenyl-3,6-dihydrodiselenin
  参考文献：
  名称：

  Quest for diatomic selenium

  摘要：

  Metallocene pentaselenides and elemental selenium were employed in an effort to generate diatomic selenium (Se2) under thermal conditions. Trapping experiments were carried out with six dienes. A successful formation of a diselenium adduct was observed in the case of 5,6-dimethylene-cyclohexa-1,3-diene (1a). The other dienes produced the corresponding dihydroselenophenes. The in-depth study of the limitations of our method to generate Se2 is described; a plausible mechanism rationalizing the observed results is proposed.

  DOI：

  10.1080/17415993.2010.513440