Diethyl-methyl-phosphane; hydrochloride | 116447-95-1

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: Diethyl-methyl-phosphane; hydrochloride
• 英文别名: Diethyl(methyl)phosphane;hydrochloride
• CAS: 116447-95-1
• 化学式: C₅H₁₃P*ClH
• 分子量: 140.593
• InChiKey: ONOQHXJJYVTZRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.56
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (1-chloro-5-methyl-1λ5-phospha-5-silabicyclo[3.3.1]nonan-1-yl)-diethylphosphane 、 甲醇 生成 Diethyl-methyl-phosphane; hydrochloride
  参考文献：
  名称：

  ISSLEIB, KURT;KRECH, FRIEDRICH;KUHNE, ULRICH, Z. CHEM., 27,(1987) N 8, 295

  摘要：

  DOI：

文献信息

• CATALYST FOR OLEFIN POLYMERIZATION AND PRODUCTION METHOD FOR POLAR GROUP-CONTAINING OLEFIN-BASED POLYMERS
  申请人：The University Of Tokyo

  公开号：EP3708593A1

  公开（公告）日：2020-09-16

  The present invention relates to a catalyst for olefin polymerization that contains a metal complex represented by general formula (C1) and a method for producing polyethylene, a copolymer of ethylene and an olefin having a polar group represented by general formula (1), or a copolymer of ethylene, an olefin having a polar group represented by general formula (1) and another monomer, using the aforementioned metal complex as a polymerization catalyst. (The symbols in the formula are as described in the description.) The metal complex catalyst of the present invention has high heat resistance and catalytic activity. As a result of using this catalyst, olefin-based polymers having a polar group can be produced efficiently that can be used in various applications by copolymerizing a nonpolar olefin (ethylene) and an olefin having a polar group at high temperatures.

  本发明涉及一种含有通式（C1）表示的金属络合物的烯烃聚合催化剂，以及使用上述金属络合物作为聚合催化剂生产聚乙烯、乙烯和具有通式（1）表示的极性基团的烯烃的共聚物，或乙烯、具有通式（1）表示的极性基团的烯烃和另一种单体的共聚物的方法。 (本发明的金属络合物催化剂具有很高的耐热性和催化活性。使用这种催化剂的结果是，通过在高温下使非极性烯烃（乙烯）和具有极性基团的烯烃共聚，可以有效地生产出具有极性基团的烯烃基聚合物，这些聚合物可用于各种用途。
• Catalyst for olefin polymerization and production method for polar group-containing olefin-based polymers
  申请人：THE UNIVERSITY OF TOKYO

  公开号：US11352453B2

  公开（公告）日：2022-06-07

  A catalyst for olefin polymerization that contains a metal complex represented by general formula (C1) and a method for producing polyethylene, a copolymer of ethylene and an olefin having a polar group represented by general formula (1), or a copolymer of ethylene, an olefin having a polar group represented by general formula (1) and another monomer, using the aforementioned metal complex as a polymerization catalyst, wherein the symbols in formula (C1) and formula (1) are as defined in the specification.

  一种含有通式（C1）表示的金属络合物的烯烃聚合催化剂，以及使用上述金属络合物作为聚合催化剂生产聚乙烯、乙烯和具有通式（1）表示的极性基团的烯烃的共聚物，或乙烯、具有通式（1）表示的极性基团的烯烃和另一种单体的共聚物的方法，其中式（C1）和式（1）中的符号如说明书中所定义。
• Issleib, Kurt; Krech, Friedrich; Kuehne, Ulrich, Zeitschrift fur Chemie, 1987, vol. 27, # 8, p. 295
  作者：Issleib, Kurt、Krech, Friedrich、Kuehne, Ulrich

  DOI：——

  日期：——