trans-meso-[Ru(trifluoroacetate)2(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)2] | 219562-99-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-meso-[Ru(trifluoroacetate)2(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)2]
• CAS: 219562-99-9
• 化学式: C₅₂H₄₈F₆O₄P₄Ru
• 分子量: 1075.91
• InChiKey: MPNALTCHHIRNRH-CQNQFFSQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-meso-[Ru(trifluoroacetate)2(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)2] 以 二氯甲烷 为溶剂， 生成 cis-(+/-)-[Ru(trifluoroacetate)2(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)2]
  参考文献：
  名称：

  New Bis-biphosphole−Transition-Metal Complexes:  Spontaneous Isomerization of trans-meso- into cis-(±)-[Ru(trifluoroacetate)₂(1,1‘-diphenyl-3,3‘,4,4‘- tetramethyl-2,2‘-biphosphole)₂]

  摘要：

  The reaction of [Ru-2(O2CCF3)(2)(mu-O2CCF3)(2)(COD)(2)(mu-H2O)] with 1,1'-diphenyl-3,4,4'-tetramethyl-2,2'-biphosphole (I) provides trans-meso-[Ru(trifluoroacetate)(2)(1,1'-diphenyl-3,3',4,4'-tetramethyl-2;2'- biphosphole)(2)] complex 3, which spontaneously isomerizes in solution into cis-(+/-)-[Ru(trifluoroacetate)(2)(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)(2)] complex 4. These new bis-biphosphole-ruthenium complexes have been characterized by X-ray diffraction.

  DOI：

  10.1021/om980667i
• 作为产物：
  描述：

  [Ru2(O2CCF3)2(μ-O2CCF3)2(C8H12)2(μ-H2O)] 、 3,3',4,4'-tetramethyl-1,1'-diphenyl-2,2'-bisphosphole 以 二氯甲烷 为溶剂， 以40%的产率得到trans-meso-[Ru(trifluoroacetate)2(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)2]
  参考文献：
  名称：

  New Bis-biphosphole−Transition-Metal Complexes:  Spontaneous Isomerization of trans-meso- into cis-(±)-[Ru(trifluoroacetate)₂(1,1‘-diphenyl-3,3‘,4,4‘- tetramethyl-2,2‘-biphosphole)₂]

  摘要：

  The reaction of [Ru-2(O2CCF3)(2)(mu-O2CCF3)(2)(COD)(2)(mu-H2O)] with 1,1'-diphenyl-3,4,4'-tetramethyl-2,2'-biphosphole (I) provides trans-meso-[Ru(trifluoroacetate)(2)(1,1'-diphenyl-3,3',4,4'-tetramethyl-2;2'- biphosphole)(2)] complex 3, which spontaneously isomerizes in solution into cis-(+/-)-[Ru(trifluoroacetate)(2)(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)(2)] complex 4. These new bis-biphosphole-ruthenium complexes have been characterized by X-ray diffraction.

  DOI：

  10.1021/om980667i