disodium tetrachlorophthalate | 50807-86-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: disodium tetrachlorophthalate
• 英文别名: sodium tetrachlorophthalate；tetrachloro-phthalic acid ; disodium-salt；Tetrachlor-phthalsaeure; Dinatrium-Salz
• CAS: 50807-86-8
• 化学式: C₈Cl₄O₄*2Na
• 分子量: 347.877
• InChiKey: FPLLCODLDVXOKQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.97
• 重原子数：
  17.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.26
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  disodium tetrachlorophthalate 以 水 为溶剂， 生成 bis-[ammino-tetrachlorophthalate-silver di-ammino-silver]di-hydrate
  参考文献：
  名称：

  Unusual silver coordination by mono-carboxylate utilization of a poly-carboxylate anion, solid-state structures of silver-tetrachlorophthalate with phthalazine and amine ligands

  摘要：

  Silver carboxylate coordination with the tetrachlorophthalate anion, in combination with neutral donor ligands, has been found to deviate from other known poly-carboxylate complexes. Both complexes reported here, bis-[tetrachlorophthalato-silver phthalazine] and bis-[ammino-tetrachlorophthato-silver di-ammino-silver], utilize mixed carboxylate bonding types for silver coordination. In the case of the phthalazine ligand, both chelating and monodentate carboxylates form the framework for the oligomeric structure. In the case of the ammine ligand, one carboxylate forms a monodentate connection to a silver-ammine group, while the other is simply involved with hydrogen bonding to lock in a [(Ag-NH3)(2)-Ag-NH3] substructure with an adjacent tetrachlorophthalato-silver unit. Both structures exhibit supramolecular connections via hydrogen bonding and pi-pi interactions. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.08.031

文献信息

• Novel two-dimensional copper(II) complexes containing tetrachloro-phthalate dianion, dicyanamide or pyrazole
  作者：Mao Liang、Dai-Zheng Liao、Zong-Hui Jiang、Shi-Ping Yan、Peng Cheng

  DOI：10.1016/j.inoche.2003.10.033

  日期：2004.2

  Abstract Two novel two-dimensional copper(II) complexes, [Cu(tcph)dca] · Hpip (1) (H2tcph=tetrachloro-phthalic acid, dca=dicyanamide anion, pip=piperidine) and [Cu(tcph)(pz)2] (2) (pz=pyrazole), have been synthesized and characterized structurally. The spectroscopic properties have also been discussed.

  摘要 两种新型二维铜(II)配合物，[Cu(tcph)dca] · Hpip (1) (H2tcph=四氯邻苯二甲酸，dca=双氰胺阴离子，pip=哌啶)和[Cu(tcph)(pz) 2] (2) (pz=吡唑)，已经合成并在结构上表征。还讨论了光谱特性。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sc: MVol.D5, 1.2.21, page 213 - 213
  作者：

  DOI：——

  日期：——
• Wenger, P. E.; Kapetanidis, I., Recueil des Travaux Chimiques des Pays-Bas, 1960, vol. 79, p. 567 - 573
  作者：Wenger, P. E.、Kapetanidis, I.

  DOI：——

  日期：——
• Tetrachlorophthalic Anhydride, Acid, and Salts
  作者：Francis E. Lawlor

  DOI：10.1021/ie50455a006

  日期：1947.11