[Zn(o-hydroxybenzoate)2(1,2-dimethylimidazole)2] | 700375-30-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Zn(o-hydroxybenzoate)2(1,2-dimethylimidazole)2]
• 英文别名: [Zn(Hsal)2(1,2-diMeim)2]
• CAS: 700375-30-0
• 化学式: C₂₄H₂₆N₄O₆Zn
• 分子量: 531.884
• InChiKey: UCBOPPRYSZLUQM-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Zn(o-hydroxybenzoate)2(1,2-dimethylimidazole)2] 以 neat (no solvent) 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  Zinc(II) di(o-hydroxybenzoate) complexes with imidazole and its derivativesSynthesis, thermal characterization and molecular structures

  摘要：

  Mixed complexes of the type: Zn(Hsal)(2)(Him)(2), Zn(Hsal)(2)(Him)(5), Zn(Hsal)(2)(4-MeHim)(2) and Zn(Hsal)(2)(1,2-diMeim)(2) (where Hsal=OHC6H4COO-, Him=imidazole, 4-MeHim=4-methylimidazole, 1,2-diMeim=1,2-dimethylimidazole) have been synthesized. The application of chemical, thermal and X-ray methods has enabled us to analyze the complexes and their sinters. The gaseous products of pyrolysis of Zn(Hsal)(2)(Him)(2) and Zn(Hsal)(2)(4-MeHim)(2) have been investigated. Thermal decomposition pathways have been postulated for synthesized complexes. The molecular structures of the Zn(Hsal)(2)(Him)(2) and Zn(Hsal)(2)(1,2-diMeim)(2) have been solved.

  DOI：

  10.1023/b:jtan.0000011021.41412.4a
• 作为产物：
  描述：

  1,2-二甲基咪唑 、 zinc di(o-hydroxybenzoate) dihydrate 以 水 为溶剂， 生成 [Zn(o-hydroxybenzoate)2(1,2-dimethylimidazole)2]
  参考文献：
  名称：

  Zinc(II) di(o-hydroxybenzoate) complexes with imidazole and its derivativesSynthesis, thermal characterization and molecular structures

  摘要：

  Mixed complexes of the type: Zn(Hsal)(2)(Him)(2), Zn(Hsal)(2)(Him)(5), Zn(Hsal)(2)(4-MeHim)(2) and Zn(Hsal)(2)(1,2-diMeim)(2) (where Hsal=OHC6H4COO-, Him=imidazole, 4-MeHim=4-methylimidazole, 1,2-diMeim=1,2-dimethylimidazole) have been synthesized. The application of chemical, thermal and X-ray methods has enabled us to analyze the complexes and their sinters. The gaseous products of pyrolysis of Zn(Hsal)(2)(Him)(2) and Zn(Hsal)(2)(4-MeHim)(2) have been investigated. Thermal decomposition pathways have been postulated for synthesized complexes. The molecular structures of the Zn(Hsal)(2)(Him)(2) and Zn(Hsal)(2)(1,2-diMeim)(2) have been solved.

  DOI：

  10.1023/b:jtan.0000011021.41412.4a