(2,2'-bipyridine)ReCl4 | 17099-98-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (2,2'-bipyridine)ReCl4
• 英文别名: [ReCl4(2,2'-bipyridine)]；ReCl4(2,2'-bipyridine)；[ReCl4(bipy)]；ReCl4(bpy)
• CAS: 17099-98-8
• 化学式: C₁₀H₈Cl₄N₂Re
• 分子量: 484.206
• InChiKey: MORHEAXMZWPUGH-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2,2'-bipyridine)ReCl4 在 triphenylphosphine 作用下， 以 二乙二醇二甲醚 为溶剂， 以65%的产率得到fac-trichloro(2,2'-bipyridyl)(PPh3)rhenium(III)
  参考文献：
  名称：

  Caspar, Jonathan V.; Sullivan, B. Patrick; Meyer, Thomas J., Inorganic Chemistry, 1984, vol. 23, # 14, p. 2104 - 2109

  摘要：

  DOI：
• 作为产物：
  描述：

  α-α'-bipyridyl, {ReCl6}-salt 以 neat (no solvent, solid phase) 为溶剂， 以>99的产率得到(2,2'-bipyridine)ReCl4
  参考文献：
  名称：

  Caspar, Jonathan V.; Sullivan, B. Patrick; Meyer, Thomas J., Inorganic Chemistry, 1984, vol. 23, # 14, p. 2104 - 2109

  摘要：

  DOI：

文献信息

• Rhenium(iv) compounds inducing apoptosis in cancer cells
  作者：José Martínez-Lillo、Teresa F. Mastropietro、Rosamaria Lappano、Antonio Madeo、Marta E. Alberto、Nino Russo、Marcello Maggiolini、Giovanni De Munno

  DOI：10.1039/c1cc11038a

  日期：——

  The anticancer properties of a series of mononuclear Re(IV) compounds of formula ReCl(4)L (where L is bpy = 2,2'-bipyridine; bpym = 2,2'-bipyrimidine; dmbpy = 4,4'-dimethyl-2,2'-bipyridine; phen = 1,10-phenanthroline) were investigated for the first time. All compounds displayed potent in vitro antiproliferative activity against selected cancer cells.

  一系列式ReCl（4）L的单核Re（IV）化合物的抗癌特性（其中L是bpy = 2,2'-联吡啶; bpym = 2,2'-联嘧啶; dmbpy = 4,4'-二甲基-2,2'-联吡啶； phen = 1,10-菲咯啉）为首次研究。所有化合物均对选定的癌细胞显示出有效的体外抗增殖活性。
• Herrmann, Wolfgang A,; Thiel, Werner R.; Herdtweck, Eberhartd, Chemische Berichte, 1990, vol. 123, # 2, p. 271 - 276
  作者：Herrmann, Wolfgang A,、Thiel, Werner R.、Herdtweck, Eberhartd

  DOI：——

  日期：——
• Magneto-structural study on a series of rhenium(IV) complexes containing biimH2, pyim and bipy ligands
  作者：José Martínez-Lillo、Donatella Armentano、Giovanni De Munno、Juan Faus

  DOI：10.1016/j.poly.2008.01.012

  日期：2008.4

  Three rhenium(IV) mononuclear compounds of formulae [ReCl4(biimH(2))]center dot 2DMF (1), [ReCl4(pyim)] center dot DMF (2) and [ReCl4(bipy)] (3) (biimH(2) = 2,2'-biimidazole, pyim = 2-(2'-pyridyl)imidazole, bipy = 2,2'-bipyridine and DMF = N,N-dimethylformamide) have been prepared and characterized. The crystal structure of 2 was determined by single crystal X-ray diffraction. Compound 2 crystallizes in the monoclinic system with P2(1)/c as space group. The rhenium atom is six-coordinated by four Cl atoms and two nitrogen atoms from a bidentate pyim ligand [average values of Re-Cl and Re-N bonds lengths being 2.330(2) and 2.117(4) angstrom, respectively]. The magnetic properties were investigated from susceptibility measurements performed on polycrystalline samples of 1-3 in the temperature range 1.9-300 K. The magnetic behaviour found is typical of antiferromagnetically coupled systems, and they,exhibit susceptibility maxima at 2.8 (1 and 2) and 5.6 K (3). Short Re-IV-Cl center dot center dot center dot Cl-Re-IV contacts through space account for the antiferromagnetic behaviour observed. (C) 2008 Elsevier Ltd. All rights reserved.