2-(4-tert.butylphenoxy)-cyclohexyl-propargyl sulfite | 19594-26-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4-tert.butylphenoxy)-cyclohexyl-propargyl sulfite
• 英文别名: 3-[2-(4-Tert-butylphenoxy)cyclohexyl]prop-2-ynyl hydrogen sulfite
• CAS: 19594-26-4
• 化学式: C₁₉H₂₆O₄S
• 分子量: 350.479
• InChiKey: VWQJSFWQHHAGKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  75
• 氢给体数：
  1
• 氢受体数：
  5

文献信息

• Insecticidal and acaricidal composition, and methods of using the same
  申请人：AGRO-KANESHO CO., LTD.

  公开号：US20020156115A1

  公开（公告）日：2002-10-24

  The present invention provides an insecticidal or acaricidal composition having an excellent pesticidal effect and a high safety, containing, as an active ingredient, a pyrazolyl compound of the following general formula (I): 1 wherein A represents a hydrogen atom; an alkyl group which may be substituted; an alkenyl group which may be substituted; an alkynyl group which may be substituted; a tri-substituted silyl group substituted with an alkyl group and/or an aryl group: an aryl group which may be substituted; or a heterocyclic group which may be substituted; B represents a single bond; a group of the formula: —(G 1 ) n —G 2 —(G 1 ) m — wherein G 1 represents an oxygen atom, a sulfur atom, a sulfinyl group or a sulfonyl group, G 2 represents an alkylene group, an alkenylene group or an alkynylene group, and n and m are independent from each other and represent 0 or 1; carbonyl group; a group of the formula: —CH 2 —O—N═C(R 3 )— wherein R 3 represents a hydrogen atom, an alkyl group or a haloalkyl group; or a group of the formula: —CH═N—O—(CR 3 R 4 ) n — wherein R 3 and R 4 each represents a hydrogen atom, an alkyl group or a haloalkyl group; and n is 0 or 1, R 1 represents a hydrogen atom; a halogen atom, an alkyl group which may be substituted; an alkenyl group which may be substituted; an alkynyl group which may be substituted; an alkoxyl group which may be substituted; or an aryl group which may be substituted, R 2 represents a hydrogen atom; an alkyl group; a haloalkyl group; or an aryl group which may be substituted, and D represents a group of the formula: —C(═Y)COX wherein X represents a hydroxyl group, an alkoxyl group or an alkylamino group, Y represents a group of the formula: CH—(G 3 ) n —G 4 — wherein G 3 represents an oxygen atom or a sulfur atom, G 4 represents an alkyl group or a haloalkyl group, and n represents 0 or 1, a group of the formula: N—O—G 4 wherein G 4 represents an alkyl group or a haloalkyl group; or a group of the formula: —N(R 5 )CO 2 G 5 wherein R 5 represents an alkyl group, an alkenyl group, an alkynyl group, an alkylthioalkyl group or an alkoxyalkyl group, and G 5 represents an alkyl group.

  本发明提供了一种具有优异杀虫或杀螨效果且具有高安全性的杀虫剂或杀螨剂组合物，其包含以下通式（I）的吡唑基化合物作为活性成分：其中A代表氢原子；可以被取代的烷基基团；可以被取代的烯基基团；可以被取代的炔基基团；取代的三取代硅基团，取代的烷基基团和/或芳基团；可以被取代的芳基团；或可以被取代的杂环基团；B代表单键；具有以下结构的基团：—（G1）n—G2—（G1）m—其中G1代表氧原子、硫原子、亚硫酰基或磺酰基，G2代表烷基基团、烯基基团或炔基基团，n和m是独立的，表示0或1；羰基基团；具有以下结构的基团：—CH2—O—N═C(R3)—其中R3代表氢原子、烷基基团或卤代烷基基团；或具有以下结构的基团：—CH═N—O—（CR3R4）n—其中R3和R4各自代表氢原子、烷基基团或卤代烷基基团；n为0或1，R1代表氢原子；卤素原子、可以被取代的烷基基团；可以被取代的烯基基团；可以被取代的炔基基团；可以被取代的烷氧基基团；或可以被取代的芳基团；R2代表氢原子；烷基基团；卤代烷基基团；或可以被取代的芳基团，D代表以下结构的基团：—C(═Y)COX，其中X代表羟基、烷氧基或烷基氨基，Y代表结构：CH—（G3）n—G4—其中G3代表氧原子或硫原子，G4代表烷基基团或卤代烷基基团，n代表0或1，具有以下结构的基团：N—O—G4其中G4代表烷基基团或卤代烷基基团；或具有以下结构的基团：—N(R5)CO2G5其中R5代表烷基基团、烯基基团、炔基基团、烷基硫基基团或烷氧基烷基基团，G5代表烷基基团。
• Insecticidal and acaricidal agent
  申请人：AGRO-KANESHO CO., LTD.

  公开号：US20030191171A1

  公开（公告）日：2003-10-09

  The present invention provides an insecticidal or acaricidal composition having an excellent pesticidal effect and a high safety, containing, as an active ingredient, a pyrazolyl compound of the following general formula (I): 1 wherein A represents a hydrogen atom; an alkyl group which may be substituted; an alkenyl group which may be substituted; an alkynyl group which may be substituted; a tri-substituted silyl group substituted with an alkyl group and/or an aryl group: an aryl group which may be substituted; or a heterocyclic group which may be substituted; B represents a single bond; a group of the formula: -(G 1 ) n -G 2 -(G 1 ) m - wherein G 1 represents an oxygen atom, a sulfur atom, a sulfinyl group or a sulfonyl group, G 2 represents an alkylene group, an alkenylene group or an alkynylene group, and n and m are independent from each other and represent 0 or 1; carbonyl group; a group of the formula: —CH 2 —O—N═C(R 3 )— wherein R 3 represents a hydrogen atom, an alkyl group or a haloalkyl group; or a group of the formula: —CH═N—O—(CR 3 R 4 ) n — wherein R 3 and R 4 each represents a hydrogen atom, an alkyl group or a haloalkyl group; and n is 0 or 1, R 1 represents a hydrogen atom; a halogen atom, an alkyl group which may be substituted; an alkenyl group which may be substituted; an alkynyl group which may be substituted; an alkoxyl group which may be substituted; or an aryl group which may be substituted, R 2 represents a hydrogen atom; an alkyl group; a haloalkyl group; or an aryl group which may be substituted, and D represents a group of the formula: —C(═Y)COX wherein X represents a hydroxyl group, an alkoxyl group or an alkylamino group, Y represents a group of the formula: CH-(G 3 ) n -G 4 - wherein G 3 represents an oxygen atom or a sulfur atom, G4 represents an alkyl group or a haloalkyl group, and n represents 0 or 1, a group of the formula: N—O-G 4 wherein G 4 represents an alkyl group or a haloalkyl group; or a group of the formula: —N(R 5 )CO 2 G 5 wherein R 5 represents an alkyl group, an alkenyl group, an alkynyl group, an alkylthioalkyl group or an alkoxyalkyl group, and G 5 represents an alkyl group.

  本发明提供了一种具有优异的杀虫或杀螨效果和高安全性的杀虫剂或杀螨剂组合物，其包含以下通式（I）的吡唑基化合物作为活性成分：其中，A表示氢原子；可以被取代的烷基基团；可以被取代的烯基基团；可以被取代的炔基基团；被取代的三取代硅基团，其被取代的基团为烷基和/或芳基；可以被取代的芳基基团；或可以被取代的杂环基团；B表示单键；一个式子的基团：-(G1)n-G2-(G1)m-，其中，G1表示氧原子、硫原子、亚砜基或磺酰基，G2表示烷基、烯基或炔基，n和m是独立的，表示0或1；羰基基团；一个式子的基团：—CH2—O—N═C(R3)—，其中，R3表示氢原子、烷基或卤代烷基；或一个式子的基团：—CH═N—O—(CR3R4)n—，其中，R3和R4分别表示氢原子、烷基或卤代烷基；n为0或1；R1表示氢原子；卤原子、可以被取代的烷基基团；可以被取代的烯基基团；可以被取代的炔基基团；可以被取代的烷氧基；或可以被取代的芳基基团；R2表示氢原子；烷基；卤代烷基；或可以被取代的芳基基团；D表示一个式子的基团：—C(═Y)COX，其中，X表示羟基、烷氧基或烷基氨基基团，Y表示一个式子的基团：CH-(G3)n-G4-，其中，G3表示氧原子或硫原子，G4表示烷基或卤代烷基，n表示0或1；一个式子的基团：N—O-G4，其中，G4表示烷基或卤代烷基；或一个式子的基团：—N(R5)CO2G5，其中，R5表示烷基、烯基、炔基、烷硫基烷基或烷氧基烷基，G5表示烷基。
• Method of making highly adsorptive polymers
  申请人：Biosys, Inc.

  公开号：EP0417910A2

  公开（公告）日：1991-03-20

  A method of forming a highly adsorptive polymer. which includes the steps of: a) homogeneously mixing a solution of a monomer consisting exclusively of one or more types of polyunsaturated monomer, a monomer solvent and an initiator, b) polymerizing the monomers to form a polymer. wherein the monomer solvent is a solvent for the monomers and a non-swelling non-solvent for the polymers, and c) removing the solvent from the polymer to form a dry powder.

  一种形成高吸附性聚合物的方法，包括以下步骤：a) 均匀混合完全由一种或多种类型的多不饱和单体、单体溶剂和引发剂组成的单体溶液；b) 使单体聚合形成聚合物，其中单体溶剂是单体的溶剂，而聚合物是不溶胀的非溶剂；c) 从聚合物中除去溶剂，形成干粉。
• OPTICALLY ACTIVE METHOXYIMINOACETAMIDE DERIVATIVES, PROCESS FOR THE PREPARATION OF THEM, INTERMEDIATES THEREFOR, AND PESTICIDES CONTAINING THEM AS THE ACTIVE INGREDIENT
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0949243A1

  公开（公告）日：1999-10-13

  An optically active methoxyiminoacetamide derivative represented by the following general formula (I) (in the above general formula, Ar represents an aryl group or a heteroaryl group, Y represents a hydrogen atom, a halogen atom, a C1-C4 alkyl group, a C1-C4 haloalkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkoxy group, a C1-C4 alkylthio group, a C2-C6 alkynyloxy group, a cyano group, a nitro group or an aryl group and n is an integer of 1 to 3), wherein its angle of rotation shows a negative value in chloroform has markedly excellent activities as agricultural chemicals.

  由以下通式（I）代表的光学活性甲氧基亚氨基乙酰胺衍生物 (在上述通式中，Ar 代表芳基或杂芳基，Y 代表氢原子、卤素原子、C1-C4 烷基、C1-C4 卤代烷基、C1-C4 烷氧基、C1-C4 卤代烷氧基、C1-C4 烷硫基、C2-C6 炔氧基、氰基、硝基或芳基，n 为 1 至 3 的整数），其中它在氯仿中的旋转角为负值，具有明显优异的农用化学品活性。
• INSECTICIDAL AND ACARICIDAL AGENTS
  申请人：Agro-Kanesho Co., Ltd.

  公开号：EP1219173A1

  公开（公告）日：2002-07-03

  The present invention provides an insecticidal or acaricidal agent having an excellent pesticidal effect and a high safety. Namely, the present invention resides in an insecticidal or acaricidal agent comprising, as an active ingredient, a pyrazolyl derivative of the following general formula (I): wherein A represents a hydrogen atom; an alkyl group which may be substituted; an alkenyl group which may be substituted; an alkynyl group which may be substituted; a tri-substituted silyl group substituted with an alkyl group and/or an aryl group: an aryl group which may be substituted; or a heterocyclic group which may be substituted; B represents a single bond; a group of the formula: -(G1)n-G2-(G1)m- wherein G1 represents an oxygen atom, a sulfur atom, a sulfinyl group or a sulfonyl group, G2 represents an alkylene group, an alkenylene group or an alkynylene group, and n and m are independent from each other and represent 0 or 1; carbonyl group; a group of the formula: -CH2-O-N=C(R3)-wherein R3 represents a hydrogen atom, an alkyl group or a haloalkyl group; or a group of the formula: -CH=N-O-(CR3R4)n- wherein R3 and R4 each represents a hydrogen atom, an alkyl group or a haloalkyl group; and n is 0 or 1, R1 represents a hydrogen atom; a halogen atom, an alkyl group which may be substituted; an alkenyl group which may be substituted; an alkynyl group which may be substituted; an alkoxyl group which may be substituted; or an aryl group which may be substituted, R2 represents a hydrogen atom; an alkyl group; a haloalkyl group; or an aryl group which may be substituted, and D represents a group of the formula: -C(=Y)COX wherein X represents a hydroxyl group, an alkoxyl group or an alkylamino group, Y represents a group of the formula: CH-(G3)n-G4 wherein G3 represents an oxygen atom or a sulfur atom, G4 represents an alkyl group or a haloalkyl group, and n represents 0 or 1, a group of the formula: N-O-G4 wherein G4 represents an alkyl group or a haloalkyl group; or a group of the formula: -N(R5)CO2G5 wherein R5 represents an alkyl group, an alkenyl group, an alkynyl group, an alkylthioalkyl group or an alkoxyalkyl group, and G5 represents an alkyl group.

  本发明提供了一种杀虫或杀螨剂，具有极佳的杀虫效果和极高的安全性。即，本发明涉及一种杀虫或杀螨剂，其活性成分包括以下通式（I）的吡唑衍生物： 式中 A 代表氢原子；可被取代的烷基；可被取代的烯基；可被取代的炔基；被烷基和/或 芳基取代的三取代硅烷基；可被取代的芳基；或可被取代的杂环基； B 代表单键；式中的基团：-(G1)n-G2-(G1)m-，其中 G1 代表氧原子、硫原子、亚砜基或磺酰基，G2 代表亚烯基、亚烯基或亚炔基，n 和 m 互不相关，代表 0 或 1；羰基；式中的基团：-CH2-O-N=C(R3)-其中 R3 代表氢原子、烷基或卤代烷基；或式中的基团：-CH=N-O-(CR3R4)n-，其中 R3 和 R4 分别代表氢原子、烷基或卤代烷基；且 n 为 0 或 1，R1 代表氢原子、卤素原子、可被取代的烷基、可被取代的烯基、可被取代的炔基或卤代烷基；R2 代表氢原子、烷基、卤代烷基或可被取代的芳基，D 代表式中的一个基团：-其中 X 代表羟基、烷氧基或烷基氨基，Y 代表式中的一个基团：CH-(G3)n-G4，其中 G3 代表氧原子或硫原子，G4 代表烷基或卤代烷基，且 n 代表 0 或 1，代表式中的一个基团：N-O-G4，其中 G4 代表烷基或卤代烷基；或式中的基团：-N(R5)CO2G5，其中 R5 代表烷基、烯基、炔基、烷硫基或烷氧烷基，G5 代表烷基。