(1-ethyl-3-methylimidazolium )[Co(trimesate)] | 951026-20-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1-ethyl-3-methylimidazolium )[Co(trimesate)]
• 英文别名: (EMIm)[Co(tma)]；(1-ethyl-3-methylimidazolium)Co(trimesate)；(EMIm)Co(TMA)
• CAS: 951026-20-3
• 化学式: C₆H₁₁N₂*C₉H₃O₆*Co
• 分子量: 377.279
• InChiKey: CONLEHKFXZWJSB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -2.89
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  129.2
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  均苯三甲酸 、 cobalt(II) diacetate tetrahydrate 、 1-乙基-3-甲基溴化咪唑 、 1-乙基-3-甲基咪唑啉双(三氟甲基磺酰基)亚胺 以 neat (no solvent) 为溶剂， 以65%的产率得到(1-ethyl-3-methylimidazolium )[Co(trimesate)]
  参考文献：
  名称：

  Anion Control in the Ionothermal Synthesis of Coordination Polymers

  摘要：

  Two anionic 3D coordination frameworks (EMIm)(2)[Co-3(TMA)(2)(OAc)(2)] 1 and (EMIm)[Co(TMA)] 2, one condensed hydroxide network [Co-5(OH)(2)(OAc)(8)](H2O)(x) 3, and one 2D layer compound (EMIm)[Co-2(TMA)(4)H-7(22bpy)(2)] 4 were prepared from three relevant ionic liquids of 1-ethyl 3-methyl imidazolium bromide (EMIm-Br), EMIm bistriflamide (EMIm-Tf2N), and mixtures of the two. The use of anions in ionic liquids plays a significant role in solvent polarity/hydrophibicity, which in turn controls the structures of materials formed in the ionothermal synthesis. The use of mixed anion ionic liquids opens up many possibilities to further tailor the properties of ionic liquids for ionothermal synthesis applications. The ionic liquid anions are not incorporated into the resultant materials.

  DOI：

  10.1021/ja0737671