ethoxycarbonyl-phosphonic acid diallyl ester | 59682-16-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: ethoxycarbonyl-phosphonic acid diallyl ester
• 英文别名: Aethoxycarbonyl-phosphonsaeure-diallylester；Ethyl bis(prop-2-enoxy)phosphorylformate
• CAS: 59682-16-5
• 化学式: C₉H₁₅O₅P
• 分子量: 234.189
• InChiKey: XURZYNUEJOPTLU-UHFFFAOYSA-N

物化性质

• 沸点：
  153-154 °C(Press: 12 Torr)
• 密度：
  1.1396 g/cm3(Temp: 0 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  氯甲酸乙酯 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醚 作用下， 生成 ethoxycarbonyl-phosphonic acid diallyl ester
  参考文献：
  名称：

  Schugurowa; Kamai, Zhurnal Obshchei Khimii, 1951, vol. 21, p. 658,660; engl. Ausg. S. 727, 728

  摘要：

  DOI：

文献信息

• Kamai; Kuchtin, Zhurnal Obshchei Khimii, 1954, vol. 24, p. 1855,1859;engl.Ausg.S.1819,1821
  作者：Kamai、Kuchtin

  DOI：——

  日期：——
• NONAQUEOUS ELECTROLYTE SOLUTION, ELECTRICITY STORAGE DEVICE USING SAME, AND PHOSPHONOFORMIC ACID COMPOUND USED IN SAME
  申请人：UBE INDUSTRIES, LTD

  公开号：US20160315351A1

  公开（公告）日：2016-10-27

  The present invention provides a nonaqueous electrolytic solution capable of suppressing worsening of heat stability of a negative electrode and improving safety of an energy storage device while maintaining high-load charging and discharging cycle properties at a high temperature, an energy storage device using the same, and a phosphonoformic acid compound to be used for the same. The nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent contains 0.001 to 5% by mass of at least one selected from a phosphonoformic acid compound having at least one carbon-carbon unsaturated bond, which is represented by the following general formula (I), and a phosphonoformic acid compound having a carbon-carbon unsaturated bond or two phosphonocarbonyl groups, which is represented by the following general formula (II). In the formula (I), each of R 1 to R 3 is an aliphatic organic group, provided that at least one of R 1 to R 3 represents a carbon-carbon unsaturated bond-containing aliphatic organic group. In the formula (II), each of R 4 and R 5 represents an alkyl group, a cycloalkyl group, or an aryl group, and R 4 and R 5 may be bonded to each other to form a ring structure. m represents 1 or 2; when m is 1, then R 6 represents an aryl group; when m is 2, then R 6 represents an alkylene group, an alkenylene group, or an alkynylene group; and a part of hydrogen atoms of R 4 to R 6 may be substituted with a halogen atom.
• Schugurowa; Kamai, Zhurnal Obshchei Khimii, 1951, vol. 21, p. 658,660; engl. Ausg. S. 727, 728
  作者：Schugurowa、Kamai

  DOI：——

  日期：——