butyl 2-(naphth-2-yl)hydrazinecarbodithiolate | 1138320-51-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: butyl 2-(naphth-2-yl)hydrazinecarbodithiolate
• 英文别名: N'-naphthalen-2-yl-hydrazinecarbodithioic acid butyl ester；N'-(naphthalen-2-yl)hydrazinecarbodithioic acid n-butyl ester；butyl 2-(naphth-2-yl)hydrazinecarbodithioate；butyl N-(naphthalen-2-ylamino)carbamodithioate
• CAS: 1138320-51-0
• 化学式: C₁₅H₁₈N₂S₂
• 分子量: 290.453
• InChiKey: UGWUYZAZZHGWBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  81.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二硫化碳 、 对甲苯磺酸正丁酯 、 2-萘肼 在 苄基三甲基氢氧化铵 作用下， 以 二甲基亚砜 为溶剂， 反应 3.58h， 以83%的产率得到butyl 2-(naphth-2-yl)hydrazinecarbodithiolate
  参考文献：
  名称：

  Triton-B-Catalyzed, Efficient, One-Pot Synthesis of Dithiocarbazates Through Alcoholic Tosylates

  摘要：

  A quick, efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various tosylates of primary, secondary, and tertiary alcohols with a variety of substituted hydrazines using the benzyl-trimethylammonium hydroxide (Triton-B)/CS2 system. The reaction conditions are mild with simpler workup procedures than the reported methods.

  DOI：

  10.1080/00397910802519141

文献信息

• Efficient TBAI-CS₂ Promoted Synthesis of Substituted Hydrazinecarbodithiolates
  作者：Nitin Srivastava

  DOI：10.1080/00304948.2022.2111171

  日期：2022.11.2

  Published in Organic Preparations and Procedures International: The New Journal for Organic Synthesis (Vol. 54, No. 6, 2022)

  发表于国际有机制剂和程序：有机合成新期刊（印刷前，2022 年）
• An Efficient, Basic Resin-Mediated, One-Pot Synthesis of Dithiocarbazates Through Alcoholic Tosylates
  作者：Devdutt Chaturvedi、Nisha Mishra、Amit K. Chaturvdi、Virendra Mishra

  DOI：10.1080/10426500802203137

  日期：2009.3.10

  A quick and efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various alcoholic tosylates of primary, secondary, and tertiary alcohols, with substituted hydrazines using an Amberlite IRA 400 (basic resin)/CS2 system. The reaction conditions are mild with simpler work-up procedures than previously reported methods.
• Triton-B catalyzed, efficient one-pot synthesis of dithiocarbazates
  作者：Devdutt Chaturvedi、Nisha Mishra、Virendra Mishra

  DOI：10.1007/s00706-008-0873-9

  日期：2008.9

  A quick and efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various primary, secondary, and tert. alkyl halides with a variety of substituted hydrazines using the benzyl-trimethylammonium hydroxide (Triton-B)/CS2 system. The reaction conditions are mild with simpler work-up procedures than the reported methods.