[Tb(picrate)3(2-bis(dibutylcarbamoylmethyl)amino)-N,N-dibutylacetamide)] | 610313-78-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Tb(picrate)3(2-bis(dibutylcarbamoylmethyl)amino)-N,N-dibutylacetamide)]
• CAS: 610313-78-5
• 化学式: C₄₈H₆₆N₁₃O₂₄Tb
• 分子量: 1368.05
• InChiKey: YAJHUTJEFQPYAB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  terbium(III) picrate 、 2-(bis-dibutylcarbamoylmethyl-amino)-N,N-dibutyl-acetamide 以 乙醇 为溶剂， 生成 [Tb(picrate)3(2-bis(dibutylcarbamoylmethyl)amino)-N,N-dibutylacetamide)]
  参考文献：
  名称：

  Synthesis, characterization of 2-(bis-dibutylcarbamoylmethyl-amino)-N, N-dibutyl-acetamide (L) lanthanide picrate complexes (Ln=Nd, Eu, Tb) and the crystal structure of [Tb(pic)3L]

  摘要：

  Solid complexes of lanthanide picrate with the ligand 2-(bis-dibutylcarbamoylmethyl-amino)-N, N-dibutyl-acetamide (L), [Ln(PiC)(3)L] (Ln = Nd, Eu, Th), have been prepared and characterized by elemental analysis, conductivity measurements, DTA and TGA analysis, IR and H-1 NMR spectra. For the terbium complex, X-ray measurements show that Tb(III) ion is 9-coordinated by three oxygen atoms and one nitrogen atom of L and five oxygen atoms of picrate groups. Molecule B has a clockwise structure due to the screw coordination arrangement of the tripod-type ligand. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00368-5