3,5-bis-dodecylbenzyl alcohol | 1590422-53-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-bis-dodecylbenzyl alcohol
• 英文别名: (3,5-Didodecylphenyl)methanol
• CAS: 1590422-53-9
• 化学式: C₃₁H₅₆O
• 分子量: 444.785
• InChiKey: KTASMECYGZGRFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.5
• 重原子数：
  32
• 可旋转键数：
  23
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3,5-bis-dodecylbenzyl alcohol 、 [4-pyrene-1-butoxy]monomalonyl acid 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 13.0h， 生成 [3,5-bis(dodecyl)benzyl]-[4-(pyren-1-yl)butoxy]malonyl ester
  参考文献：
  名称：

  Pyrene-Fullerene C60 Dyads as Light-Harvesting Antennas

  摘要：

  一系列含有芡烯单元的芡烯-富勒烯C60二聚体（PyFC12、PyFPy、Py2FC12和PyFN）被合成并进行了表征。通过吸收和荧光光谱学研究了它们的光学性质。这样设计二聚体是因为芡烯作为光捕获分子，能够产生“单体”（PyFC12）或激基复合物发射（PyFPy、Py2FC12和PyFN）。这些二聚体的荧光光谱显示出芡烯单体和激基复合物发射量的显著减少，而无需出现新的发射带，这是因为富勒烯C60的存在。研究发现，芡烯的荧光猝灭几乎是定量的，具体取决于构造方式，其猝灭程度在96%至99%之间。这表明能量从激发的芡烯物种之一转移到了富勒烯C60。

  DOI：

  10.3390/molecules19010352

文献信息

• Narrow band gap conjugated polymers employing cross-conjugated donors useful in electronic devices
  申请人：The University of Southern Mississippi

  公开号：US11312819B2

  公开（公告）日：2022-04-26

  The invention provides for new polymer compounds and methods for the preparation of modular narrow band gap conjugated compounds and polymers that incorporate exocyclic cross-conjugated donors or substituents, as well as novel monomer components of such polymers and the resulting products which comprise materials and useful electronic devices with novel functionality.

  本发明提供了新的聚合物化合物和制备模块化窄带隙共轭化合物和聚合物的方法，这些化合物和聚合物含有外环交联共轭供体或取代基，以及此类聚合物的新型单体成分和由此产生的产品，这些产品包括具有新型功能的材料和有用的电子设备。
• NARROW BAND GAP CONJUGATED POLYMERS EMPLOYING CROSS-CONJUGATED DONORS USEFUL IN ELECTRONIC DEVICES
  申请人：Azoulay, Jason D.

  公开号：EP3504259A2

  公开（公告）日：2019-07-03
• Narrow Band Gap Conjugated Polymers Employing Cross-Conjugated Donors Useful in Electronic Devices
  申请人：Azoulay Jason D.

  公开号：US20190194385A1

  公开（公告）日：2019-06-27

  The invention provides for new polymer compounds and methods for the preparation of modular narrow band gap conjugated compounds and polymers that incorporate exocyclic cross-conjugated donors or substituents, as well as novel monomer components of such polymers and the resulting products which comprise materials and useful electronic devices with novel functionality.
• Narrow Band Gap Conjugated Polymers Employing Cross-Conjugated Donors Useful In Electronic Devices
  申请人：THE UNIVERSITY OF SOUTHERN MISSISSIPPI

  公开号：US20220332870A1

  公开（公告）日：2022-10-20

  The invention provides for new polymer compounds and methods for the preparation of modular narrow band gap conjugated compounds and polymers that incorporate exocyclic cross-conjugated donors or substituents, as well as novel monomer components of such polymers and the resulting products which comprise materials and useful electronic devices with novel functionality.
• [EN] NARROW BAND GAP CONJUGATED POLYMERS EMPLOYING CROSS-CONJUGATED DONORS USEFUL IN ELECTRONIC DEVICES<br/>[FR] POLYMÈRES CONJUGUÉS À LARGEUR DE BANDE INTERDITE ÉTROITE UTILISANT DES DONNEURS À CONJUGAISON CROISÉE UTILES DANS DES DISPOSITIFS ÉLECTRONIQUES
  申请人：AZOULAY JASON D

  公开号：WO2018039347A2

  公开（公告）日：2018-03-01

  The invention provides for new polymer compounds and methods for the preparation of modular narrow band gap conjugated compounds and polymers that incorporate exocyclic cross-conjugated donors or substituents, as well as novel monomer components of such polymers and the resulting products which comprise materials and useful electronic devices with novel functionality.