| 31814-06-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 31814-06-9
• 化学式: C₁₆H₁₆CuN₂O₄
• 分子量: 363.86
• InChiKey: KIWSKNZVVIFFKN-WJTRLQBQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2'-羟基苯乙酮 在 盐酸羟胺 、 sodium acetate 作用下， 以 乙醇 、 水 为溶剂， 反应 3.25h， 生成
  参考文献：
  名称：

  酚肟酸铜（II）配合物顺磁NMR参数的计算和实验测量。

  摘要：

  我们提出了一种使用DFT预测顺磁性双肟基铜（II）配合物的NMR光谱中异常1 H和13 C位移的策略。尽管1 H– 13 C相关光谱表明，完整的实验仍需要结合实验和理论方法，但我们与实验测量结果显示出良好的一致性。

  DOI：

  10.1039/c7cc05098d

文献信息

• Spectral and ESR features of some copper(II) chelates with 2-hydroxyaryloximes
  作者：Maria Lalia-Kantouri、Manolis Hartophylles

  DOI：10.1016/s0277-5387(00)86011-8

  日期：1992.1

  Copper(II) complexes of 2-hydroxyaryloximes were synthesized and characterized on the basis of elemental analyses, molecular weight determinations, conductivity and magnetic moment measurements, and ESR, IR and electronic absorption (in solutions and in solid state) spectroscopy. Implications of the magnetic and spectral data in relation to the structures of the complexes are discussed. Solvent effects are also considered.
• Thermal behaviour and kinetic analysis of the thermogravimetric data of some copper(II), nickel(II), and palladium(II) 2-hydroxyaryloximates
  作者：M. Lalia-Kantouri、M. Hartophylles

  DOI：10.1016/0040-6031(93)80170-f

  日期：1993.9

  The thermal stability and mode of decomposition of eleven 2-hydroxyaryloxime chelates with the transition metals Cu(II), Ni(II), and Pd(II) have been studied in air atmosphere using the TG/DTA technique. In the case of copper chelates, their thermal behaviour was also studied in nitrogen atmosphere by TG/DTG.A kinetic analysis of the TG data was performed using the Coats-Redfern method to determine the apparent activation energies and the pre-exponential factor of the Arrhenius equation. Mass spectrometry was also used and possible fragmentation patterns are given and discussed.