1,3-phenylene bis(3-((bis(diethylamino)phosphaneyl)oxy)phenyl) bis(diethylphosphoramidite) | 332350-79-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-phenylene bis(3-((bis(diethylamino)phosphaneyl)oxy)phenyl) bis(diethylphosphoramidite)
• CAS: 332350-79-5
• 化学式: C₄₂H₇₂N₆O₆P₄
• 分子量: 880.965
• InChiKey: JCPDCLDEPXJSNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.32
• 重原子数：
  58.0
• 可旋转键数：
  30.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  74.82
• 氢给体数：
  0.0
• 氢受体数：
  12.0

反应信息

• 作为反应物：
  描述：

  Diethyl-phosphoramidous acid 3-[diethylamino-(3-hydroxy-phenoxy)-phosphanyloxy]-phenyl ester 3-hydroxy-phenyl ester 、 1,3-phenylene bis(3-((bis(diethylamino)phosphaneyl)oxy)phenyl) bis(diethylphosphoramidite) 以 乙腈 为溶剂， 生成 N3,N3,N7,N7,N11,N11,N15,N15,N19,N19,N23,N23-dodecaethyl-2,4,6,8,10,12,14,16,18,20,22,24-dodecaoxa-3,7,11,15,19,23-hexaphospha-1,5,9,13,17,21(1,3)-hexabenzenacyclotetracosaphane-3,7,11,15,19,23-hexaamine
  参考文献：
  名称：

  Synthesis of Penta- and Hexa-m-Phenylenecyclophosphites and Thiophosphates

  摘要：

  New representatives of an original crown ether class-penta- and hexaresorcinolamidophosphites (7a,b and 13a,b)-were synthesized using the molecular assemblage technique. Their thio derivatives (8a,b and 14a,b) were obtained, as well as the rhodium (I) complex of hexaphosphite 13b (16). Macrocycle 15 containing both P3+ and P5+ was synthesized, H-1 and P-31 NMR spectroscopy data suggested the higher conformational flexibility of phosphite macrocycles.

  DOI：

  10.1080/10426500008076340
• 作为产物：
  描述：

  六乙基亚磷酸胺 、 Diethyl-phosphoramidous acid 3-[diethylamino-(3-hydroxy-phenoxy)-phosphanyloxy]-phenyl ester 3-hydroxy-phenyl ester 以 乙腈 为溶剂， 反应 2.0h， 生成 1,3-phenylene bis(3-((bis(diethylamino)phosphaneyl)oxy)phenyl) bis(diethylphosphoramidite)
  参考文献：
  名称：

  Synthesis of Penta- and Hexa-m-Phenylenecyclophosphites and Thiophosphates

  摘要：

  New representatives of an original crown ether class-penta- and hexaresorcinolamidophosphites (7a,b and 13a,b)-were synthesized using the molecular assemblage technique. Their thio derivatives (8a,b and 14a,b) were obtained, as well as the rhodium (I) complex of hexaphosphite 13b (16). Macrocycle 15 containing both P3+ and P5+ was synthesized, H-1 and P-31 NMR spectroscopy data suggested the higher conformational flexibility of phosphite macrocycles.

  DOI：

  10.1080/10426500008076340