silver;methyl(diphenyl)phosphane;trifluoromethanesulfonate | 278608-30-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: silver;methyl(diphenyl)phosphane;trifluoromethanesulfonate
• CAS: 278608-30-3
• 化学式: C₂₇H₂₆AgF₃O₃P₂S
• 分子量: 657.379
• InChiKey: CEHVWDDUWUULKN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver trifluoromethanesulfonate 、 二苯基甲氧基膦 以 乙醚 为溶剂， 以86%的产率得到silver;methyl(diphenyl)phosphane;trifluoromethanesulfonate
  参考文献：
  名称：

  Structural characterization of silver(I) complexes [Ag(O3SCF3)(L)] (L=PPh3, PPh2Me, SC4H8) and [AgLn](CF3SO3) (n=2–4), (L=PPh3, PPh2Me)

  摘要：

  We have studied the solution and some solid state structures of a series of trifluoromethanesulfonate silver(I) complexes, namely of formula [Ag(O3SCF3)(L)] (L = PPh3, PPh2Me, SC4H8) and [AgLn](CF3SO3) (n = 2-4, L =PPh3, PPh2Me). The solution behaviour is as expected for mononuclear silver species, although polynuclear species can not be totally ruled out in non-coordinating solvents. The solid state structures display a wide variety of nuclearities, silver co-ordination numbers and trifluoromethanesulfonate co-ordination modes, depending on the ligand L. Thus, for complexes of empirical formula [Ag(O3SCF3)(L)], the crystal structure of [Ag(O3SCF3)(PPh3)] is a trimer with bridging triflates; the molecular structure of [Ag(O3SCF3)(PPh2Me)] shows tetranuclear complexes with a 'chair' geometry, further linked into chains by Ag-phenyl interactions; and [Ag(O3SCF3)(tht)] (tht = SC4H8) crystallizes in infinite chains. For complexes of formula [Ag(O3SCF3)(L)(2)], the PPh, derivative is a dimer with two bridging triflates, and the PPh2Me derivative is a monomer. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00052-9