[Au(C2CMe2OH)(1,3,5-triaza-7-phosphaadamantane)] | 876069-40-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: [Au(C2CMe2OH)(1,3,5-triaza-7-phosphaadamantane)]
• 英文别名: Au(CCMe2OH)(1,3,5-triaza-7-phosphaadamantane)；Au(CCCMe2OH)(PTA)；gold(1+);2-methylbut-3-yn-2-ol;1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane
• CAS: 876069-40-8
• 化学式: C₁₁H₁₉AuN₃OP
• 分子量: 437.232
• InChiKey: KFJNGKVCOIDSCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [AuCl(PTA)] 、 2-甲基-3-丁炔-2-醇 在 NaOC₂H₅ 作用下， 以 乙醇 为溶剂， 以86%的产率得到[Au(C2CMe2OH)(1,3,5-triaza-7-phosphaadamantane)]
  参考文献：
  名称：

  Organometallic Gold(I) and Gold(III) Complexes Containing 1,3,5-Triaza-7-phosphaadamantane (TPA):  Examples of Water-Soluble Organometallic Gold Compounds

  摘要：

  The organometallic gold(l) complexes [Au(C equivalent to CCRR'OH)(TPA)] (R = R, = H, Me, Ph and R = Me, R' = Et) and [Au(C6F5)(TPA)] as well as the gold(Ill) complexes trans-[Au(C6F5)(2)(TPA)(2)]OTf and [Au(C6F5)(3)(TPA)] (TPA = 1,3,5-triaza-7-phosphaadamantane) were prepared and fully characterized by spectroscopic methods and, in the case of rac- [Au{C equivalent to C(Et)(Me)OH} (TPA)] and [Au(C6F5)(3)(TPA)], by X-ray crystallography. The alkynyl complexes [Au(C equivalent to CCRR'OH)(TPA)] (R = R, = H, Me and R = Me, R' = Et) represent rare examples of organometallic gold(l) complexes that are soluble and stable in water.

  DOI：

  10.1021/om050852d