| 201022-72-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 201022-72-2
• 化学式: C₁₈H₁₄Cl₂MoO₅S₂
• 分子量: 541.284
• InChiKey: QENZOVMJEXJAHP-CTKSFPOUSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(4-Chlorophenyl)-2-sulfanylpropanoic acid 、 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of molybdenum(VI)-dioxo complexes containing both coordinated thiolate and carboxylate groups. Reactions with their own free ligands

  摘要：

  The synthesis, characterization and spectroscopic properties of a group of Mo(VI) complexes having thiocarboxylate ligands of type [(MoO2)-O-VI(O2CC(S)MePh-X)(2)](2-) have been reported (X = H,p-Me,p-Cl). The peak potential for the Mo(VI) reduction increases according to the electron-donor ability of X (Me > H > Cl), Reaction of these Mo(VI) complexes with their own free ligands has been studied by ESR and UV-Vis spectroscopy, yielding the monomeric [(MoO)-O-V(O2CC(S)MePh-X)(2)](-) as unique complex products. The kinetic study of this oxidation reaction has also been investigated. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05725-3