4-methoxybenzaldehyde-N-[4-(4'-chlorophenylenesulfonyl)benzoyl]hydrazone | 689220-58-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-methoxybenzaldehyde-N-[4-(4'-chlorophenylenesulfonyl)benzoyl]hydrazone
• CAS: 689220-58-4
• 化学式: C₂₁H₁₇ClN₂O₄S
• 分子量: 428.896
• InChiKey: DOHMMPHKAJMZHI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  4-methoxybenzaldehyde-N-[4-(4'-chlorophenylenesulfonyl)benzoyl]hydrazone 、 cobalt(II) diacetate tetrahydrate 以 甲醇 为溶剂， 以65%的产率得到diaquadi(4-methoxybenzaldehyde-N-[4-(4'-chlorophenylenesulfonyl)benzoyl]hydrazone)cobalt(II) acetate
  参考文献：
  名称：

  Synthesis and Spectroscopic Studies of Cobalt(II) and Copper(II) Complex Compounds with 4‐Methoxybenzaldehyde‐N‐[4‐(4′‐chlorophenylenesulfonyl)benzoyl]hydrazone

  摘要：

  New complex compounds of Co(II) and Cu(II) with 4-methoxybenzaidehyde-N-[4-(4'-chlorophenylenesulfonyl)benzoyl]hydrazone (HL) have been prepared and characterized by elemental and thermogravimetrical analyses, magnetic susceptibility measurements, infrared, electronic and EPR spectra. The ligand coordinates in either the keto or the enol form, depending on the experimental conditions. Cobalt acetate gives a monomeric, distorted-octahedral compound, while cobalt chloride forms a monomeric penta-coordinate complex. Copper acetate and copper chloride form dimeric complexes, a monomeric compound having been obtained from copper bromide.

  DOI：

  10.1081/sim-120026557