2-(2'-ClC6H4CH2NCH)C10H7 | 420134-55-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(2'-ClC6H4CH2NCH)C10H7
• 英文别名: N-[(2-chlorophenyl)methyl]-1-naphthalen-2-ylmethanimine
• CAS: 420134-55-0
• 化学式: C₁₈H₁₄ClN
• 分子量: 279.769
• InChiKey: SOQCTJNEXKAIQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(2'-ClC6H4CH2NCH)C10H7 以 丙酮 为溶剂， 生成 [PtMe(2-(2'-ClC6H4CH2NCH)C10H6)PPh3]*2H2O
  参考文献：
  名称：

  Regioselective activation of CH bonds of naphthyl imines at platinum(II). Crystal structures of [PtMe{1-(2′-ClC6H4CH2NCH)C10H6}PPh3] and [PtMe{2-(2′-ClC6H4CH2NCH)C10H6}PPh3]

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(Me2NCH2CH2NCH)C10H7 (2a) and 2-(Me2NCH2CH2NCH)C10H7 (2b) carried out in acetone at room temperature produced compounds [PtMe2 {1-(Me2NCH2CH2NCH)C10H7}] (3a) and [PtMe2{1- (Me2NCH2CH2NCH)C10H7}] (3b), respectively, in which the imines act as bidentate [N,N] ligands. cyclometallated [C,N,N'] compounds [PtMe{1-(Me2NCH2CH2NCH)C10H6}] (4a) and [PtMe{2-(Me2NCH2CH2NCH)C10H6}] (4b) were obtained by refluxing toluene solutions of compounds 3a or 3b. Reaction Of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(2'-ClC6H4CH2NCH)C10H7 (2c) and 2-(2'-ClC6H4CH2NCH)C10H7 (2d) produced straightforward metallation to yield [PtMe{1-(2'-ClC6H2CH2NCH)C10H6}SMe2] (5c) and [PtMe{2-(2'-ClC6H4CH2NCH)C10H6}SMe2] (5d) containing a [CN] ligand. Triphenylphosphine derivatives [PtMe{1-(2'-ClC6H4CH2NCH)C10H6} PPh3] (6c) and [PtMe{2-(2'-ClC6H4CH2NCH)C(10)H6}PPh3] (6d) were also prepared. All compounds were characterised by NMR spectroscopics and 6e and 6d were also characterised crystallographically. For both [CN,N'] and [CN] systems, the metallation took place regioselectively at beta-positions of the naphthyl group, (C) 2002 Elsevier Science BN. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01230-x
• 作为产物：
  描述：

  2-萘甲醛 、 邻氯苯甲胺 以 甲苯 为溶剂， 反应 1.0h， 以82%的产率得到2-(2'-ClC6H4CH2NCH)C10H7
  参考文献：
  名称：

  Regioselective activation of CH bonds of naphthyl imines at platinum(II). Crystal structures of [PtMe{1-(2′-ClC6H4CH2NCH)C10H6}PPh3] and [PtMe{2-(2′-ClC6H4CH2NCH)C10H6}PPh3]

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(Me2NCH2CH2NCH)C10H7 (2a) and 2-(Me2NCH2CH2NCH)C10H7 (2b) carried out in acetone at room temperature produced compounds [PtMe2 {1-(Me2NCH2CH2NCH)C10H7}] (3a) and [PtMe2{1- (Me2NCH2CH2NCH)C10H7}] (3b), respectively, in which the imines act as bidentate [N,N] ligands. cyclometallated [C,N,N'] compounds [PtMe{1-(Me2NCH2CH2NCH)C10H6}] (4a) and [PtMe{2-(Me2NCH2CH2NCH)C10H6}] (4b) were obtained by refluxing toluene solutions of compounds 3a or 3b. Reaction Of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(2'-ClC6H4CH2NCH)C10H7 (2c) and 2-(2'-ClC6H4CH2NCH)C10H7 (2d) produced straightforward metallation to yield [PtMe{1-(2'-ClC6H2CH2NCH)C10H6}SMe2] (5c) and [PtMe{2-(2'-ClC6H4CH2NCH)C10H6}SMe2] (5d) containing a [CN] ligand. Triphenylphosphine derivatives [PtMe{1-(2'-ClC6H4CH2NCH)C10H6} PPh3] (6c) and [PtMe{2-(2'-ClC6H4CH2NCH)C(10)H6}PPh3] (6d) were also prepared. All compounds were characterised by NMR spectroscopics and 6e and 6d were also characterised crystallographically. For both [CN,N'] and [CN] systems, the metallation took place regioselectively at beta-positions of the naphthyl group, (C) 2002 Elsevier Science BN. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01230-x

文献信息

• Regioselective activation of CH bonds of naphthyl imines at platinum(II). Crystal structures of [PtMe{1-(2′-ClC6H4CH2NCH)C10H6}PPh3] and [PtMe{2-(2′-ClC6H4CH2NCH)C10H6}PPh3]
  作者：Margarita Crespo、Mercè Font-Bardı́a、Sonia Pérez、Xavier Solans

  DOI：10.1016/s0022-328x(01)01230-x

  日期：2002.1

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(Me2NCH2CH2NCH)C10H7 (2a) and 2-(Me2NCH2CH2NCH)C10H7 (2b) carried out in acetone at room temperature produced compounds [PtMe2 1-(Me2NCH2CH2NCH)C10H7}] (3a) and [PtMe21- (Me2NCH2CH2NCH)C10H7}] (3b), respectively, in which the imines act as bidentate [N,N] ligands. cyclometallated [C,N,N'] compounds [PtMe1-(Me2NCH2CH2NCH)C10H6}] (4a) and [PtMe2-(Me2NCH2CH2NCH)C10H6}] (4b) were obtained by refluxing toluene solutions of compounds 3a or 3b. Reaction Of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(2'-ClC6H4CH2NCH)C10H7 (2c) and 2-(2'-ClC6H4CH2NCH)C10H7 (2d) produced straightforward metallation to yield [PtMe1-(2'-ClC6H2CH2NCH)C10H6}SMe2] (5c) and [PtMe2-(2'-ClC6H4CH2NCH)C10H6}SMe2] (5d) containing a [CN] ligand. Triphenylphosphine derivatives [PtMe1-(2'-ClC6H4CH2NCH)C10H6} PPh3] (6c) and [PtMe2-(2'-ClC6H4CH2NCH)C(10)H6}PPh3] (6d) were also prepared. All compounds were characterised by NMR spectroscopics and 6e and 6d were also characterised crystallographically. For both [CN,N'] and [CN] systems, the metallation took place regioselectively at beta-positions of the naphthyl group, (C) 2002 Elsevier Science BN. All rights reserved.