vinyl 1-naphthoate | 7561-15-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: vinyl 1-naphthoate
• 英文别名: Ethenyl naphthalene-1-carboxylate
• CAS: 7561-15-1
• 化学式: C₁₃H₁₀O₂
• 分子量: 198.221
• InChiKey: BGVWGPMAGMJLBU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  vinyl 1-naphthoate 、 亚磷酸二乙酯 在 tetraethylammonium hexafluorophosphate 、 三乙胺 作用下， 以 N-甲基吡咯烷酮 、 N,N-二甲基甲酰胺 为溶剂， 以78%的产率得到1-(diethoxyphosphoryl)ethyl 1-naphthoate
  参考文献：
  名称：

  富电子烯烃的电化学诱导马尔科夫尼科夫型选择性加氢/氘代膦酰化

  摘要：

  通过无金属电化学诱导策略实现了富电子烯烃与 P(O)H 化合物的区域选择性加氢/氘代膦酰化，以高产率获得各种马尔科夫尼科夫型加合物。随后通过添加D 2 O作为D源，获得了一系列具有高氘（D）掺入的单氘化有机磷化合物。该协议具有广泛的衬底范围、低能耗、高原子经济性和可扩展性。单氘代有机磷酸可通过后期转化合成。

  DOI：

  10.1039/d2cc04729b
• 作为产物：
  描述：

  1-萘甲酸 在 cadmium(II) oxide 作用下， 生成 vinyl 1-naphthoate
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：

文献信息

• Reusable rhodium catalyst for the selective transvinylation of sp 2 -C linked carboxylic acid
  作者：Ruihang Jiang、Zhangpei Chen、Kun Zhan、Lei Liu、Junjie Zhou、Yongjian Ai、Shuang Li、Hongjie Bao、Ze'nan Hu、Li Qi、Jingting Wang、Hong-bin Sun

  DOI：10.1016/j.tetlet.2018.07.039

  日期：2018.8

  The vinyl benzoate derivatives were successfully synthesized by the transvinylation reactions that vinyl group transferred from vinyl acetate to aromatic carboxylic acids with the recoverable catalyst RhCl3·3H2O. This catalyst features air stable and tolerance of water, good reusable ability, meanwhile, shows high selectivity for aromatic carboxylic acid in the presence of phenolic hydroxyl. With this

  通过可回收的催化剂RhCl 3 ·3H 2 O通过乙酸乙烯酯将乙烯基转移至芳族羧酸的转乙烯基反应成功地合成了苯甲酸乙烯酯衍生物。该催化剂具有空气稳定性和耐水性，同时具有良好的可重复使用能力，显示出在酚羟基存在下对芳族羧酸具有高选择性。使用这种方法，可以以高达95％的收率生产各种苯甲酸乙烯酯衍生物。
• Allyl terminated macromolecular monomers of polyethers
  申请人：The B.F. GOODRICH Company

  公开号：EP0218079A2

  公开（公告）日：1987-04-15

  A cationic ring-opening polymerization of a cylic ether ("CE") in conjunction with an unsaturated alcohol (propagator) having an allyl double bond, produces a polyether macromer having an allylic group near one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the CE to the OH group which is the propagating species. The CE is an alkylene oxide or an aliphatic or aromatic glycidyl ether; the propa­gator is a primary or secondary alcohol which, if cyclic may have a single internal double bond in one ring. The catalyst is a Friedel-Crafts acid, strong protic organic or inorganic acid, oxonium salt, or the like. The macromer formed may be homopolymerized to yield a poly­vinyl homomacromer with pendant chains of polymerized CE; or the CE may be copolymerized with a wide variety of olefinically unsaturated monomers to form a macromer copolymer; or, plural cyclic ethers may be (a) sequenti­ally polymerized to form macromer block copolyethers, or, (b) polymerized randomly to form macromer copoly­ether copolymers. The cationically ring-opened macromer formed always contains a trace of a cyclic oligomer of the CE.

  环状醚（"CE"）与具有烯丙基双键的不饱和醇（促进剂）进行阳离子开环聚合，可产生一种聚醚大分子，其一端附近具有烯丙基，另一端具有羟基。聚合反应是通过 CE 与羟基的加成反应进行的。CE 是环氧亚烷基或脂肪族或芳香族缩水甘油醚；繁殖体是伯醇或仲醇，如果是环状的，可能在一个环上有一个内部双键。催化剂为 Friedel-Crafts 酸、强质子有机酸或无机酸、羰基鎓盐或类似物质。形成的大单体可进行均聚，生成具有聚合 CE 下垂链的聚乙烯均大单体；或将 CE 与多种烯烃不饱和单体共聚，形成大单体共聚物；或将多个环醚 (a) 顺序聚合，形成大单体嵌段共聚物，或 (b) 随机聚合，形成大单体共聚醚共聚物。形成的阳离子开环大单体总是含有微量的 CE 环状低聚物。
• Styryl terminated macromolecular monomers of polyethers
  申请人：The B.F. GOODRICH Company

  公开号：EP0221551A2

  公开（公告）日：1987-05-13

  A cationic ring-opening polymerization of a cylic ether ("CE") in conjunction with an unsaturated alcohol (propagator) having a styryl or substituted styryl group, produces a polyether macromer having the styryl group near one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the CE to the OH group which is the propagating species. The CE is an alkylene oxide or an aliphatic or aromatic gly­cidyl ether; the propagator is a primary or secondary alcohol. The catalyst is a Friedel-Crafts acid, strong protic organic or inorganic acid, oxonium salt, or the like. Plural cyclic ethers may be (a) sequentially polymerized to form macromer block copolyethers, or, (b) polymerized randomly to form macromer copolyether co­polymers. The cationically ring-opened macromer formed always contains a trace of a cyclic oligomer of the CE. The macromer formed may be homopolymerized to yield a homopolymer of the macromer with pendant chains of poly­merized CE; or the macromer may be copolymerized with a wide variety of olefinically unsaturated monomers to form a copolymer of macromer.

  环状醚（"CE"）与具有苯乙烯基或取代苯乙烯基的不饱和醇（促进剂）进行阳离子开环聚合，可产生一种聚醚大单体，其一端附近具有苯乙烯基，另一端具有羟基。聚合是通过 CE 与羟基的加成反应进行的。CE 是环氧亚烷基或脂肪族或芳香族缩水甘油醚；促进剂是伯醇或仲醇。催化剂为 Friedel-Crafts 酸、强质子有机酸或无机酸、羰基鎓盐或类似物质。多元环醚可以 (a) 顺序聚合形成大单体嵌段共聚物，或 (b) 无规聚合形成大单体共聚醚共聚物。形成的阳离子开环大单体总是含有微量的 CE 环状低聚物。形成的大孔聚合体可进行均聚，生成大孔聚合体与聚合 CE 的垂链的均聚物；或将大孔聚合体与多种烯烃不饱和单体进行共聚，形成大孔聚合体的共聚物。
• Coating varnish composition and antifouling coating composition
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0711813A2

  公开（公告）日：1996-05-15

  A coating varnish composition comprising a biodegradable polymer (A) comprising one or more kinds of constituent units (b) represented by the general formula (I), (II) or (III) and one or more other kinds of constituent units (a) capable of imparting bio-degradability: wherein in the formula (I), R¹ and R are independently a hydrogen atom, a chlorine atom, a bromine atom, a methyl group, an ethyl group or a phenyl group; in the formula (II), R³ and R⁴ are independently a hydrogen atom, a chlorine atom, a bromine atom, or a substituted or unsubstituted methyl or ethyl group; in the formula (III), R⁵ and R⁶ are independently a hydrogen atom, a methyl group or an ethyl group, and R⁷ is a straight, branched or cyclic alkyl group, an aryl group, a heterocyclic group or an aralkyl group, which may have one or more substituents.

  一种涂料清漆组合物，包含一种可生物降解聚合物 (A)，该聚合物包含一种或多种由通式 (I)、(II) 或 (III) 表示的组成单元 (b) 和一种或多种可赋予生物降解性的其他组成单元 (a)： 其中，在式 (I) 中，R¹ 和 R 独立地为氢原子、氯原子、溴原子、甲基、乙基或苯基；在式 (II) 中，R³ 和 R⁴ 独立地为氢原子、氯原子、溴原子或取代或未取代的甲基或乙基；在式 (III) 中，R⁵ 和 R⁶ 独立地是氢原子、甲基或乙基，R⁷ 是直链、支链或环状烷基、芳基、杂环基或芳烷基，它们可以有一个或多个取代基。
• Cast-molding material for plastic lens and process for the production of plastic lens
  申请人：Hoya Corporation

  公开号：EP0903217A2

  公开（公告）日：1999-03-24

  A cast-molding material for a plastic lens which is almost free from causing defective dyeing when dyed, and a process for producing plastic lenses almost free from causing defective dyeing, the cast-molding material containing, as essential components, a combination of (A) diethylene glycol bisallylcarbonate or a mixture of diethylene glycol bisallylcarbonate and a monomer copolymerizable therewith, with (B) a polyether-modified silicone compound, and the process comprising cast-molding the above cast-molding material in a mold.

  一种在染色时几乎不会造成染色不良的塑料镜片浇铸成型材料，以及一种几乎不会造成染色不良的塑料镜片的生产工艺，该浇铸成型材料的主要成分是(A)二甘醇双烯丙基碳酸酯或二甘醇双烯丙基碳酸酯与可与之共聚的单体的混合物，以及(B)聚醚改性硅化合物，工艺包括在模具中浇铸成型上述浇铸成型材料。