5,10-dibutoxy-4,11-dihydro-2H-naphthoisoindole | 1415995-49-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5,10-dibutoxy-4,11-dihydro-2H-naphthoisoindole
• 英文别名: 5,10-dibutoxy-4,11-dihydro-2H-naphtho[2,3-f]isoindole
• CAS: 1415995-49-1
• 化学式: C₂₄H₂₉NO₂
• 分子量: 363.5
• InChiKey: DBXFVLBJYYFDBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  34.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5,10-dibutoxy-4,11-dihydro-2H-naphthoisoindole 、 对甲酰基苯甲酸甲酯 在 三氟化硼乙醚 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 二氯甲烷 、 四氢呋喃 为溶剂， 反应 3.5h， 以12%的产率得到
  参考文献：
  名称：

  Tetraaryltetraanthra[2,3]porphyrins: Synthesis, Structure, and Optical Properties

  摘要：

  A synthetic route to symmetrical tetraaryltetraanthra[2,3]porphyrins (Ar(4)TAPs) was developed. Ar(4)TAPs bearing various substituents in meso-phenyls and anthracene residues were prepared from the corresponding pyrrolic precursors. The synthesized porphyrins possess high solubility and exhibit remarkably strong absorption bands in the near-infrared region (790-950 nm). The scope of the method, selection of the peripheral substituents, choice of the metal, and their influence on the optical properties are discussed together with the first X-ray crystallographic data for anthraporphyrin.

  DOI：

  10.1021/jo302135q
• 作为产物：
  描述：

  9,10-di-n-butoxy-2-chloro-3-phenylsulfonyl-1,2,3,4-tetrahydroanthracene 在 potassium tert-butylate 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 potassium hydroxide 作用下， 以 四氢呋喃 、 二氯甲烷 、 乙二醇 为溶剂， 反应 6.34h， 生成 5,10-dibutoxy-4,11-dihydro-2H-naphthoisoindole
  参考文献：
  名称：

  Tetraaryltetraanthra[2,3]porphyrins: Synthesis, Structure, and Optical Properties

  摘要：

  A synthetic route to symmetrical tetraaryltetraanthra[2,3]porphyrins (Ar(4)TAPs) was developed. Ar(4)TAPs bearing various substituents in meso-phenyls and anthracene residues were prepared from the corresponding pyrrolic precursors. The synthesized porphyrins possess high solubility and exhibit remarkably strong absorption bands in the near-infrared region (790-950 nm). The scope of the method, selection of the peripheral substituents, choice of the metal, and their influence on the optical properties are discussed together with the first X-ray crystallographic data for anthraporphyrin.

  DOI：

  10.1021/jo302135q

文献信息

• Tetraaryltetraanthra[2,3]porphyrins: Synthesis, Structure, and Optical Properties
  作者：Mikhail A. Filatov、Stanislav Baluschev、Iliyana Z. Ilieva、Volker Enkelmann、Tzenka Miteva、Katharina Landfester、Sergey E. Aleshchenkov、Andrei V. Cheprakov

  DOI：10.1021/jo302135q

  日期：2012.12.21

  A synthetic route to symmetrical tetraaryltetraanthra[2,3]porphyrins (Ar(4)TAPs) was developed. Ar(4)TAPs bearing various substituents in meso-phenyls and anthracene residues were prepared from the corresponding pyrrolic precursors. The synthesized porphyrins possess high solubility and exhibit remarkably strong absorption bands in the near-infrared region (790-950 nm). The scope of the method, selection of the peripheral substituents, choice of the metal, and their influence on the optical properties are discussed together with the first X-ray crystallographic data for anthraporphyrin.