naphthalane-1,8-diamine | 250146-10-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: naphthalane-1,8-diamine
• 英文别名: 1,8-diaminodecalin；1,2,3,4,4a,5,6,7,8,8a-Decahydronaphthalene-1,8-diamine
• CAS: 250146-10-2
• 化学式: C₁₀H₂₀N₂
• 分子量: 168.282
• InChiKey: MLCQONACWQIWKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  naphthalane-1,8-diamine 、 9-芴酮 在 溶剂黄146 作用下， 以 甲醇 为溶剂， 以66 %的产率得到1'H,3'H-spiro[fluorene-9,2'-perimidine]
  参考文献：
  名称：

  Pd 催化 2-碘代联苯与碳酸亚乙烯酯成环合成 9-芴酮

  摘要：

  报道了一种钯催化的2-碘代联苯分子间选择性 C−H 环羰基化反应，其中碳酸亚乙烯酯充当一氧化碳转移剂以实现环化反应。

  DOI：

  10.1002/asia.202301040

文献信息

• Novel nitric oxide-releasing amidine diazeniumdiolates, compositions and uses thereof and method of making same
  申请人：Government of the United States of America, represented by the Secretary

  公开号：US20040014720A1

  公开（公告）日：2004-01-22

  The present invention relates to nitric oxide-releasing amidine diazeniumdiolates, compositions comprising same, methods of using same, and a method for preparing same from imidate diazeniumdiolates and primary or secondary amines.

  本发明涉及一种释放一氧化氮的胺基偶氮二醇酸盐，包括该物质的组合物，使用该物质的方法，以及从亚胺酸偶氮二醇酸盐和一级或二级胺制备该物质的方法。
• An extended polymer composition derived from grafted elastomers and polypropylene
  申请人：Bridgestone Corporation

  公开号：EP0879831A1

  公开（公告）日：1998-11-25

  There are disclosed a gel or polymer composition which comprises 100 parts by weight of: a graft copolymer composition formed from the graft reaction of a maleate functionalized ethylene-alpha-olefin copolymer and a maleate functionalized polypropylene with an organic diamine grafting agent, and at least 30 parts by weight of an extender oil or a low molecular weight organic component. These gel compositions have super soft properties, heat resistance, and/or damping properties.

  本发明公开了一种凝胶或聚合物组合物，该组合物包含 100 重量份的以下成分：马来酸盐官能化乙烯-α-烯烃共聚物和马来酸盐官能化聚丙烯与有机二胺接枝剂接枝反应形成的接枝共聚物组合物，以及至少 30 重量份的延伸油或低分子量有机成分。这些凝胶组合物具有超软特性、耐热性和/或阻尼特性。
• High damping gel derived from extending grafted elastomers and polypropylene
  申请人：Bridgestone Corporation

  公开号：EP0879832A1

  公开（公告）日：1998-11-25

  There is disclosed a gel or polymer composition containing: 100 parts by weight of a graft copolymer composition formed by the reaction of an organic diamine grafting agents with maleate functional groups on an elastomeric block containing block copolymer and with maleate functional groups on polypropylene, and at least 30 parts by weight of an extender oil or a low molecular weight organic component. These gel compositions have super soft properties, heat resistance, and/or damping properties.

  本发明公开了一种凝胶或聚合物组合物，其中含有：100 重量份的接枝共聚物组合物（由有机二胺接枝剂与含嵌段共聚物的弹性嵌段上的马来酸酯官能团以及与聚丙烯上的马来酸酯官能团反应形成），以及至少 30 重量份的扩展剂油或低分子量有机成分。这些凝胶组合物具有超软特性、耐热性和/或阻尼特性。
• Gels derived from extending grafted centipede polymers and polypropylene
  申请人：Bridgestone Corporation

  公开号：EP0955316A1

  公开（公告）日：1999-11-10

  The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.

  本发明传授了一种可形成高阻尼软聚合物凝胶的方法。该方法包括：在基本干燥的条件下，将聚（烯基苯共马来酰亚胺）聚合物与马来酸化聚亚烷基和烷基二胺反应，足以形成聚亚烷基接枝聚（烯基苯共马来酰亚胺）聚合物产品；以及，将聚亚烷基接枝聚（烯基苯共马来酰亚胺）聚合物产品与足以形成凝胶的扩展剂油分散。本发明还考虑了一种聚合物凝胶组合物、一种聚合物组合物和一种用该聚合物凝胶组合物制造的物品。
• Centipede polymers grafted with hydrogenated block copolymers and polypropylene and gels thereof
  申请人：Bridgestone Corporation

  公开号：EP0955329A1

  公开（公告）日：1999-11-10

  The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and a maleated hydrogenated block copolymer and an alkyl diamine grafting agent under substantially dry conditions sufficient to form a hydrogenated block copolymer-polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the hydrogenated block copolymer-polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.

  本发明传授了一种可形成高阻尼软聚合物凝胶的方法。该方法包括：在基本干燥的条件下，将聚（烯基苯共马来酰亚胺）聚合物与马来酰化聚亚烷基和马来酰化氢化嵌段共聚物以及烷基二胺接枝剂反应，足以形成氢化嵌段共聚物-聚亚烷基接枝聚（烯基苯共马来酰亚胺）聚合物产品；以及，将氢化嵌段共聚物-聚亚烷基接枝聚（烯基苯共马来酰亚胺）聚合物产品与足以形成凝胶的扩展油分散。本发明还考虑了一种聚合物凝胶组合物、一种聚合物组合物和一种用该聚合物凝胶组合物制造的物品。