10-[4-(N-phenyl-2-benzimidazolyl)phenyl]phenothiazine | 888009-19-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-[4-(N-phenyl-2-benzimidazolyl)phenyl]phenothiazine
• 英文别名: 10-[4-(1-phenylbenzimidazol-2-yl)phenyl]phenothiazine
• CAS: 888009-19-6
• 化学式: C₃₁H₂₁N₃S
• 分子量: 467.594
• InChiKey: BBIQTORXVRLJHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  35
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  10-[4-(N-phenyl-2-benzimidazolyl)phenyl]phenothiazine 、 间氯过氧苯甲酸 、 氢氧化钾 在 二氯甲烷 、 水 、 crude product 、 溶剂黄146 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 生成 10-[4-(N-Phenyl-2-benzimidazolyl)phenyl]phenothiazine 5,5-dioxide
  参考文献：
  名称：

  Use Of Phenothiazine-S-Oxides And Phenothiazine -S,S-Dioxides In The Form Of Matrix Materials For Organic Light-Emitting Diodes

  摘要：

  本发明涉及使用苯并噻嗪S-氧化物和S,S-二氧化物作为有机发光二极管的基质材料，特别是作为有机发光二极管的发光层中的基质材料，涉及包含至少一种苯并噻嗪S-氧化物或S,S-二氧化物作为基质材料以及至少一种分布在其中作为发射体的其他物质的发光层的有机发光二极管，涉及包含至少一种苯并噻嗪S-氧化物或S,S-二氧化物作为基质材料以及至少一种分布在其中作为发射体的其他物质的发光层，涉及由一种或多种苯并噻嗪S-氧化物或S,S-二氧化物作为基质材料以及至少一种分布在其中作为基质材料的其他物质组成的发光层，涉及包括相应发光层的有机发光二极管，以及涉及包括相应有机发光二极管的设备。

  公开号：

  US20080018238A1

文献信息

• Phenothiazines, S-Oxides, And S,S-Dioxides As Well As Phenoxazines As Emitters For Oleds
  申请人：Gessner Thomas

  公开号：US20100308714A1

  公开（公告）日：2010-12-09

  The use of phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivatives as emitter substances in organic light-emitting diodes, an organic light-emitting diode comprising a light-emitting layer, the light-emitting layer comprising at least one phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, and a light-emitting layer comprising or consisting of the aforementioned phenoxazine, phenothiazine-phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, a hole- and exciton-blocking layer comprising or consisting of the aforementioned phenoxazine derivative, phenothiazine derivative, phenothiazine S-oxide derivative or phenothiazine S,S-dioxide derivative, and a device which comprises an inventive organic light-emitting diode. The present invention further relates to specific phenothiazine S,S-dioxide derivatives, phenothiazine S-oxide derivatives and phenothiazine derivatives and production processes thereof, and to their use in organic light-emitting diodes.

  使用苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为有机发光二极管中的发射物质，一种有机发光二极管包括一个发光层，该发光层至少包括一种苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为发射物质，以及一个包含或由上述苯氧嗪、苯噻嗪、苯噻嗪S-氧化物或苯噻嗪S,S-二氧化物衍生物作为发射物质的发光层，一个包含或由上述苯氧嗪衍生物、苯噻嗪衍生物、苯噻嗪S-氧化物衍生物或苯噻嗪S,S-二氧化物衍生物的空穴和激子阻挡层，以及包含创新有机发光二极管的器件。本发明还涉及特定的苯噻嗪S,S-二氧化物衍生物、苯噻嗪S-氧化物衍生物和苯噻嗪衍生物及其生产工艺，以及它们在有机发光二极管中的使用。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20180205019A1

  公开（公告）日：2018-07-19

  An organic electroluminescence device including a first electrode, a hole transport region on the first electrode, an emission layer on the hole transport region, an electron transport region on the emission layer, and a second electrode on the electron transport region, wherein the hole transport region includes a first heterocyclic compound including 1 to 3 structures derived from a compound represented by Formula 1 below, and the emission layer includes a second heterocyclic compound including 1 or 2 structures derived from a compound represented by Formula 1.

  一种有机电致发光器件，包括第一电极、设置在第一电极上的空穴传输区域、设置在空穴传输区域上的发射层、设置在发射层上的电子传输区域，以及设置在电子传输区域上的第二电极，其中空穴传输区域包括第一杂环化合物，该化合物包括根据下面的化合物1表示的化合物衍生的1到3个结构，发射层包括第二杂环化合物，该化合物包括根据化合物1表示的化合物衍生的1或2个结构。
• LIGHT EMITTING MATERIAL, COMPOUND, AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：KYUSHU UNIVERSITY NATIONAL UNIVERSITY CORP.

  公开号：US20150239880A1

  公开（公告）日：2015-08-27

  To provide a material useful as a light emitting material of an organic light emitting device. A light emitting material comprising a compound represented by the general formula (1) wherein X represents O, S, N—R 11 , C═O, C(R 12 )(R 13 ), or Si(R 14 )(R 15 ); Y represents O, S, or N—R 16 ; Ar 1 represents a substituted or unsubstituted arylene group, and Ar 2 represents an aromatic ring or a heteroaromatic ring; and R 1 to R 8 and R 11 to R 16 each independently represent a hydrogen atom or a substituent.

  为提供一种用作有机发光器件的发光材料的材料。该发光材料包括由通式（1）所表示的化合物，其中X代表O、S、N—R11、C═O、C(R12)(R13)或Si(R14)(R15)；Y代表O、S或N—R16；Ar1代表取代或未取代的芳烃基团，Ar2代表芳香环或杂芳环；R1到R8和R11到R16各自独立地表示氢原子或取代基。
• Phenothiazines, S-oxides, and S,S-dioxides as well as phenoxazines as emitters for OLEDs
  申请人：BASF Aktiengesellschaft

  公开号：US08029919B2

  公开（公告）日：2011-10-04

  The use of phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivatives as emitter substances in organic light-emitting diodes, an organic light-emitting diode comprising a light-emitting layer, the light-emitting layer comprising at least one phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, and a light-emitting layer comprising or consisting of the aforementioned phenoxazine, phenothiazine-phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, a hole- and exciton-blocking layer comprising or consisting of the aforementioned phenoxazine derivative, phenothiazine derivative, phenothiazine S-oxide derivative or phenothiazine S,S-dioxide derivative, and a device which comprises an inventive organic light-emitting diode. The present invention further relates to specific phenothiazine S,S-dioxide derivatives, phenothiazine S-oxide derivatives and phenothiazine derivatives and production processes thereof, and to their use in organic light-emitting diodes.

  苯氧噻嗪、苯并噻嗪、苯并噻嗪S-氧化物或苯并噻嗪S,S-二氧化物衍生物作为有机发光二极管中的发射物质的使用，一种有机发光二极管包括一个发光层，该发光层至少包括一种苯氧噻嗪、苯并噻嗪、苯并噻嗪S-氧化物或苯并噻嗪S,S-二氧化物衍生物作为发射物质，并且发光层包括或由上述苯氧噻嗪、苯并噻嗪、苯并噻嗪S-氧化物或苯并噻嗪S,S-二氧化物衍生物作为发射物质，一个孔和激子阻挡层包括或由上述苯氧噻嗪衍生物、苯并噻嗪衍生物、苯并噻嗪S-氧化物衍生物或苯并噻嗪S,S-二氧化物衍生物组成，以及包括创新有机发光二极管的装置。本发明还涉及特定的苯并噻嗪S,S-二氧化物衍生物、苯并噻嗪S-氧化物衍生物和苯并噻嗪衍生物及其制备过程，并且涉及它们在有机发光二极管中的使用。
• Organic electroluminescent device
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US10862047B2

  公开（公告）日：2020-12-08

  An organic electroluminescent device having an anode, a cathode, and a light emitting layer between the anode and the cathode, in which the light emitting layer contains a first organic compound, a second organic compound, and a third organic compound that satisfy the following expression (A), the second organic compound is a delayed fluorescent material, and the third organic compound is a light emitting material, is capable of enhancing the light emission efficiency. ES1(A), ES1(B) and ES1(C) represent a lowest singlet excitation energy level of the first, second and third organic compound, respectively. ES1(A)>ES1(B)>ES1(C)  (A)

  一种有机电致发光器件具有阳极、阴极以及位于阳极和阴极之间的发光层，其中发光层包含满足以下表达式（A）的第一种有机化合物、第二种有机化合物和第三种有机化合物，第二种有机化合物是一种延迟荧光材料，第三种有机化合物是一种发光材料，该器件能够提高发光效率。ES1(A)、ES1(B) 和 ES1(C) 分别代表第一、第二和第三种有机化合物的最低单激发能级。 ES1(A)>ES1(B)>ES1(C) (A)