isobutylsulfanyl-ethene | 24345-81-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: isobutylsulfanyl-ethene
• 英文别名: Isobutyl-vinyl-sulfid；Vinylisobutylsulfid；Isobutyl-thioethen；iso-Butylthioethen；Isobutyl vinyl sulfide；1-ethenylsulfanyl-2-methylpropane
• CAS: 24345-81-1
• 化学式: C₆H₁₂S
• 分子量: 116.227
• InChiKey: CANYKRZRPKHWHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  isobutylsulfanyl-ethene 在 盐酸 作用下， 以83.5%的产率得到1-(1-chloro-ethylsulfanyl)-2-methyl-propane
  参考文献：
  名称：

  Amosova, S. V.; Gostevskaya, V. I.; Gavrilova, G. M., Journal of Organic Chemistry USSR (English Translation), 1984, vol. 20, p. 2294 - 2298

  摘要：

  DOI：

文献信息

• Regioselective Addition of Dithiophosphinic Acids to Vinyl Sulfides and Selenides: An Efficient Route Toward Functional Dithiophosphinates
  作者：Ludmila A. Oparina、Alexander V. Artem'ev、Nikita A. Kolyvanov、Oksana V. Vysotskaya、Nataliya A. Chernysheva、Vladimir I. Smirnov、Tatyana N. Borodina、Nina K. Gusarova、Boris A. Trofimov

  DOI：10.1002/hc.21215

  日期：2015.1

  Earlier unknown S-[1-(organosulfanyl)ethyl]- and S-[1-(organoselenyl)ethyl] dithiophosphinates were synthesized in 85–97% yields by regioselective addition of dithiophosphinic acids to diverse vinyl sulfides and selenides under mild conditions (ambient temperature, Et2O, 3 h).

  早期未知的 S-[1-(有机硫烷基)乙基]-和 S-[1-(有机硒基)乙基]二硫代次膦酸盐通过在温和条件下（环境温度）区域选择性地将二硫代次膦酸添加到多种乙烯基硫化物和硒化物中，以 85-97% 的产率合成。温度，Et2O，3 小时）。
• Hydrophosphorylation of vinyl sulfides with elemental phosphorus in the KOH/DMSO(H₂O) system: synthesis of 2-alkyl(aryl)thioethylphosphinic acids
  作者：B. A. Trofimov、A. V. Artem’ev、N. K. Gusarova、A. O. Sutyrina、S. F. Malysheva、L. A. Oparina

  DOI：10.1080/17415993.2017.1395027

  日期：2018.1.2

  ABSTRACT Elemental phosphorus (red or white) reacts with alkyl and aryl vinyl sulfides in the superbase system KOH/DMSO(H2O) at 75–120°C for 2–3 h to afford 2-alkyl(aryl)thioethylphosphinic acids in a yield of up to 31%. GRAPHICAL ABSTRACT

  摘要 元素磷（红色或白色）与超碱系统 KOH/DMSO(H2O) 中的烷基和芳基乙烯基硫化物在 75–120°C 下反应 2–3 小时，得到 2-烷基（芳基）硫乙基次膦酸，产率为高达 31%。图形概要
• Thermosetting compositions, thermal latent hydroxyl compounds, thermal latent thiol compounds and methods of preparation thereof
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0452841A2

  公开（公告）日：1991-10-23

  Thermosetting compositions are excellent in storage stability, useful as one component thermosetting compositions, give cured products having excellent chemical properties, physical properties and weathering resistance and favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting compositions comprise a compound having in the molecule two or more hydroxyl groups and/or thiol groups blocked by a vinyl ether compound, a vinyl thioether compound or a heterocyclic compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked hydroxyl and/or thiol compound by heating and a thermal latent acid catalyst. The blocked hydroxyl and/or thiol group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

  热固性组合物具有优异的储存稳定性，可用作单组分热固性组合物，固化后的产品具有优异的化学性质、物理性质和耐候性，可用于涂料组合物、油墨、粘合剂和模塑塑料。 热固性组合物包括一种化合物，其分子中的两个或两个以上羟基和/或硫醇基团被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基双键并以氧或硫作为杂原子的杂环化合物阻断；一种化合物，其分子中的两个或两个以上活性官能团可通过加热与被阻断的羟基和/或硫醇化合物形成化学键；以及一种热潜伏酸催化剂。第一种化合物的受阻羟基和/或硫醇基团与第二种化合物的活性官能团可包含在同一分子中。
• Thermosetting compositions, thermal latent carboxyl compounds and methods of preparation thereof
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0451738A2

  公开（公告）日：1991-10-16

  Thermosetting composition is excellent in storage stability, is useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

  热固性组合物具有出色的储存稳定性，可用作单组分热固性组合物，固化后的产品具有出色的化学性质、物理性质和耐候性，可用于涂料组合物、油墨、粘合剂和模塑塑料。 这种热固性组合物包括一种化合物，其分子中有两个或两个以上的羧基被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基双键且氧或硫为杂原子的杂化合物封住；一种化合物，其分子中有两个或两个以上的活性官能团，通过加热可与被封住的羧基化合物形成化学键；还可选择使用一种热潜伏酸催化剂。第一种化合物的封端羧基和第二种化合物的活性官能团可以包含在同一个分子中。
• Thermosetting compositions, thermal latent acid catalysts, method of coating and coated articles
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0535667A2

  公开（公告）日：1993-04-07

  Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.

  热固性组合物包括：分子中具有两个或两个以上被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基型双键且氧或硫为杂原子的杂化合物封端的羧基的化合物；具有两个或两个以上可通过加热与被封端的羧基化合物形成化学键的活性官能团的化合物；特定的乙烯基醚或乙烯基硫醚和热潜酸催化剂。第一种化合物的封端羧基和第二种化合物的活性官能团可以包含在同一个分子中。热固性组合物固化后的产品具有优异的化学性质、物理性质、耐候性和储存稳定性，可用于涂料组合物、油墨、粘合剂和模塑塑料。