6-methylpyridine-2,4-dicarboxylic acid N-oxide | 1001024-37-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6-methylpyridine-2,4-dicarboxylic acid N-oxide
• 英文别名: 6-methyl-1-oxidopyridin-1-ium-2,4-dicarboxylic acid
• CAS: 1001024-37-8
• 化学式: C₈H₇NO₅
• 分子量: 197.147
• InChiKey: ANBZYJUVEODHBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  100
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  6-methylpyridine-2,4-dicarboxylic acid N-oxide 、 2,3,4,5-四-(4-吡啶)噻吩 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以48.6%的产率得到[Zn(1,2,3,4-tetra(4-pyridyl)thiophene)(6-methylpyridine-2,4-dicarboxylate N-oxide)(H2O)]*H2O
  参考文献：
  名称：

  Synthesis, characterization and luminescent property of a novel zinc(II) 1,2,3,4-tetra(4-pyridyl)thiophene metal–organic framework

  摘要：

  A novel metal-organic framework (MOF) [Zn(TPT)(MPDCO)(H2O)center dot H2O](n) (TPT = 1,2,3,4-tetra (4-pyridyl)thiophene, MPDCO = 6-methylpyridine-2,4-dicarboxylic acid N-oxide) (1) was obtained via hydrothermal synthesis and characterized by the elemental analysis, IR spectroscopy, TG analysis, luminescent spectroscopy and single-crystal X-ray diffraction analysis. Single-crystal structural analysis reveals that a one-dimensional (1-D) ladderlike MOF is constructed through the mixed ligands, and it is further connected by the intermolecular hydrogen bonds to form a 3-D supramolecular network. Complex I exhibits efficient blue luminescence at room temperature, and the framework is stable below 235 degrees C. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.07.027

文献信息

• Catalyst compositions and catalytic processes
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0603557A1

  公开（公告）日：1994-06-29

  Catalytic compositions and catalytic processes are provided. The catalytic compositions are produced by the process that comprises contacting an organonickel compound with a cyclicazacarbyl compound. Optionally, one or more catalytic promoters can be present in the catalytic compositions. Additionally, one or more olefins can be contacted with one or more of these catalytic compositions to form oligomerization products and/or polymerization products.

  提供了催化组合物和催化工艺。催化组合物是通过将有机镍化合物与环氮羰基化合物接触的工艺生产的。催化组合物中可任选存在一种或多种催化促进剂。此外，一种或多种烯烃可与一种或多种这些催化组合物接触，以形成低聚产物和/或聚合产物。
• US5332708A
  申请人：——

  公开号：US5332708A

  公开（公告）日：1994-07-26
• US5461126A
  申请人：——

  公开号：US5461126A

  公开（公告）日：1995-10-24
• Synthesis, characterization and luminescent property of a novel zinc(II) 1,2,3,4-tetra(4-pyridyl)thiophene metal–organic framework
  作者：Ling Qiu、Jianguo Lin、Yanyan Xu

  DOI：10.1016/j.inoche.2009.07.027

  日期：2009.10

  A novel metal-organic framework (MOF) [Zn(TPT)(MPDCO)(H2O)center dot H2O](n) (TPT = 1,2,3,4-tetra (4-pyridyl)thiophene, MPDCO = 6-methylpyridine-2,4-dicarboxylic acid N-oxide) (1) was obtained via hydrothermal synthesis and characterized by the elemental analysis, IR spectroscopy, TG analysis, luminescent spectroscopy and single-crystal X-ray diffraction analysis. Single-crystal structural analysis reveals that a one-dimensional (1-D) ladderlike MOF is constructed through the mixed ligands, and it is further connected by the intermolecular hydrogen bonds to form a 3-D supramolecular network. Complex I exhibits efficient blue luminescence at room temperature, and the framework is stable below 235 degrees C. (C) 2009 Elsevier B.V. All rights reserved.