[Co(HL)₂]ClO₄*CH₃OH | 1457998-32-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Co(HL)₂]ClO₄*CH₃OH
• 英文别名: [Co(2-((2-(2-hydroxybenzylamino)ethylamino)methyl)phenol)₂]ClO₄*CH₃OH
• CAS: 1457998-32-1
• 化学式: CH₄O*C₃₂H₃₈CoN₄O₄*ClO₄
• 分子量: 733.164
• InChiKey: LMDXBKQEEMYXRA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N-双(2-羟基苯)乙烯二胺 、 cobalt(II) perchlorate hexahydrate 以 甲醇 为溶剂， 反应 3.0h， 以75%的产率得到[Co(HL)₂]ClO₄*CH₃OH
  参考文献：
  名称：

  Synthesis, spectral characterization and X-ray crystal structure of Fe(III) and Co(III) complexes with an acyclic Schiff base ligand

  摘要：

  Two complexes of composition [Co(HL)(2)]center dot ClO4 center dot CH3OH (1) and [Fe2L3]center dot 0.38H(2)O (2) (H2L = 2-((2-(2-hydroxybenzylamino)ethylamino) methyl) phenol) have been synthesized and their structures have been characterized. The mononuclear cobalt complex 1 shows the metal ion Co(III) in an octahedral environment, being coordinated to two ligand molecules in a N4O2 core, remaining one of the two hydroxyl phenol groups of each ligand not deprotonated and uncoordinated. Instead, complex 2 is dinuclear, and each of the two metal centers is coordinated by one molecule ligand and other ligand molecule acts as bridge between the two metal centers, resulting a distorted N4O2 octahedral environment for each Fe(III) ion. In this case the two hydroxyl phenol groups of the ligand molecules are deprotonated and coordinated. Variable-temperature solid-state magnetic studies have been performed for compound 2. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.07.018