3-Benzyl-6-(2-bromo-benzyliden)-1,3,4-trimethyl-piperazine-2,5-dion | 1092731-50-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-Benzyl-6-(2-bromo-benzyliden)-1,3,4-trimethyl-piperazine-2,5-dion
• 英文别名: 3-Benzyl-6-(2-bromo-benzyliden)-1,3,4-trimethyl-piperazin-2,5-dion；(6Z)-3-benzyl-6-[(2-bromophenyl)methylidene]-1,3,4-trimethylpiperazine-2,5-dione
• CAS: 1092731-50-4
• 化学式: C₂₁H₂₁BrN₂O₂
• 分子量: 413.314
• InChiKey: VSCHAIUXLZSGEE-AQTBWJFISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Herbicidally Active Composition
  申请人：Hupe Eike

  公开号：US20100190794A1

  公开（公告）日：2010-07-29

  The present invention relates to herbicidally active compositions comprising at least one piperazinedione compound of the formula I in which: R x , R y are each hydrogen or together are a chemical bond; R 1 is cyano or nitro; R 2 is hydrogen, fluorine, chlorine, C 1 -C 2 -alkyl, ethenyl or C 1 -C 2 -alkoxy; R 3 is fluorine or hydrogen; R 4 is methyl; R 5 is hydrogen, methyl or ethyl; R 6 is hydrogen, methyl or ethyl; and R 7 is hydrogen or halogen; and at least one further active compound selected from the group consisting of b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors, b5) bleacher herbicides; b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose biosynthesis inhibitors; b12) decoupler herbicides; b13) auxin herbicides; b14) auxin transport inhibitors; b15) other herbicides, and C) safeners.

  本发明涉及具有至少一种式I的哌嗪二酮化合物的除草活性组合物： 其中： Rx，Ry分别为氢或一起为化学键； R1为氰基或硝基； R2为氢、氟、氯、C1-C2-烷基、乙烯基或C1-C2-烷氧基； R3为氟或氢； R4为甲基； R5为氢、甲基或乙基； R6为氢、甲基或乙基；以及 R7为氢或卤素； 以及从以下组中选择的至少一种进一步活性化合物： b1）脂质生物合成抑制剂； b2）乙酰乳酸合成酶抑制剂（ALS抑制剂）； b3）光合作用抑制剂； b4）原卟啉原生物合成酶抑制剂； b5）漂白剂除草剂； b6）烯丙基酮酸磷酸合酶抑制剂（EPSP抑制剂）； b7）谷氨酰胺合成酶抑制剂； b8）7,8-二氢叶酸合成酶抑制剂（DHP抑制剂）； b9）有丝分裂抑制剂； b10）非常长链脂肪酸合成抑制剂（VLCFA抑制剂）； b11）纤维素生物合成抑制剂； b12）解偶联剂除草剂； b13）生长素除草剂； b14）生长素转运抑制剂； b15）其他除草剂；以及 C）安全剂。
• Piperazine Compounds Having Herbicidal Action
  申请人：Hupe Eike

  公开号：US20100173777A1

  公开（公告）日：2010-07-08

  The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R 1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R 12 , phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R 1a ; Z is a covalent bond or a CH 2 group; R 12 is hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, C 2 -C 6 -alkenyl, C 5 -C 6 -cycloalkenyl, C 2 -C 6 -alkynyl and the like; R 2 is hydrogen, halogen, nitro, cyano, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 2 -C 4 -alkenyl, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkoxy, benzyl or a group S(O) n R 21 in which R 21 is C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl and n is 0, 1 or 2; R 3 is hydrogen or halogen; R 4 is C 1 -C 4 -alkyl, C 3 -C 4 -alkenyl or C 3 -C 4 -alkynyl; R 5 is hydrogen, C 1 -C 4 -alkyl, C 3 -C 4 -alkenyl, C 3 -C 4 -alkynyl or a group C(═O)R 51 in which R 51 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy or C 1 -C 4 -haloalkoxy; R 6 is C 1 -C 4 -alkyl, C 1 -C 4 -hydroxyalkyl or C 1 -C 4 -haloalkyl; R 7 , R 8 independently of one another are hydrogen, OH, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkyloxy, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; R 9 , R 10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO 2 , C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 2 -C 4 -alkenyl, C 1 -C 4 -alkoxy and C 1 -C 4 -haloalkoxy; and R 11 is hydrogen or C 1 -C 4 -alkyl; and the agriculturally useful salts of these compounds.

  本发明涉及以下所定义的一般式I的哌嗪化合物以及它们作为除草剂的用途。此外，本发明涉及用于作物保护的组合物和控制不受欢迎的植被的方法。R1选择自卤素、氰基、硝基、Z—C(═O)—R12、苯基和具有1、2、3或4个杂原子（选自O、N和S作为环原子）的5-或6-成员杂环基团，其中苯基和杂环基团未取代或可能具有1、2、3或4个取代基R1a；Z是共价键或CH2基团；R12是氢、C1-C6-烷基、C3-C6-环烷基、C2-C6-烯基、C5-C6-环烯烃基、C2-C6-炔基等；R2是氢、卤素、硝基、氰基、C1-C4-烷基、C1-C4-卤代烷基、C2-C4-烯基、C1-C4-烷氧基、C1-C4-卤代烷氧基、苄基或S(O)nR21基团，其中R21是C1-C4-烷基或C1-C4-卤代烷基，n为0、1或2；R3是氢或卤素；R4是C1-C4-烷基、C3-C4-烯基或C3-C4-炔基；R5是氢、C1-C4-烷基、C3-C4-烯基、C3-C4-炔基或C(═O)R51基团，其中R51是氢、C1-C4-烷基、C1-C4-卤代烷基、C1-C4-烷氧基或C1-C4-卤代烷氧基；R6是C1-C4-烷基、C1-C4-羟基烷基或C1-C4-卤代烷基；R7、R8独立地是氢、羟基、C1-C4-烷氧基、C1-C4-卤代烷氧基、C1-C4-烷基或C1-C4-卤代烷基；R9、R10独立地选择自氢、卤素、氰基、硝基、C1-C4-烷基、C1-C4-卤代烷基、C2-C4-烯基、C1-C4-烷氧基和C1-C4-卤代烷氧基的基团；R11是氢或C1-C4-烷基；以及这些化合物的在农业上有用的盐。
• Piperazine Compounds Whith a Herbicidal Action
  申请人：Hupe Eike

  公开号：US20100152047A1

  公开（公告）日：2010-06-17

  The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. In formula I, the variables have the following meanings: R 1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R 11 , phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R 1a ; Z is a covalent bond or a CH 2 group; R 11 is hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, C 2 -C 6 -alkenyl, C 5 -C 6 -cycloalkenyl, C 2 -C 6 -alkynyl and the like; R 2 is hydrogen, halogen, nitro, cyano, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 2 -C 4 -alkenyl, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkoxy, benzyl or a group S(O) n R 21 in which R 21 is C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl and n is 0, 1 or 2; R 3 is hydrogen or halogen; R 4 is C 1 -C 4 -alkyl, C 3 -C 4 -alkenyl or C 3 -C 4 -alkynyl; R 5 is hydrogen, C 1 -C 4 -alkyl, C 3 -C 4 -alkenyl, C 3 -C 4 -alkynyl or a group C(═O)R 51 in which R 51 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy or C 1 -C 4 -haloalkoxy; R 6 is C 1 -C 4 -alkyl, C 1 -C 4 -hydroxyalkyl or C 1 -C 4 -haloalkyl; R 7 , R 8 independently of one another are hydrogen, OH, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkyloxy, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; and R 9 , R 10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO 2 , C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 2 -C 4 -alkenyl, C 1 -C 4 -alkoxy and C 1 -C 4 -haloalkoxy.

  本发明涉及以下所定义的通用式I的哌嗪化合物，以及它们作为除草剂的用途。此外，该发明涉及用于农作物保护的组合物和控制不受欢迎植被的方法。在式I中，变量具有以下含义：R1从卤素、氰基、硝基、Z—C(═O)—R11、苯基和具有1、2、3或4个杂原子（选自O、N和S）作为环原子的5-或6-成员杂环基中选择，其中苯基和杂环基未取代或可能具有1、2、3或4个取代基R1a；Z是一个共价键或一个CH2基团；R11是氢、C1-C6-烷基、C3-C6-环烷基、C2-C6-烯基、C5-C6-环烯基、C2-C6-炔基等；R2是氢、卤素、硝基、氰基、C1-C4-烷基、C1-C4-卤代烷基、C2-C4-烯基、C1-C4-烷氧基、C1-C4-卤代烷氧基、苄基或一个含有S(O)nR21基团，其中R21是C1-C4-烷基或C1-C4-卤代烷基，n为0、1或2；R3是氢或卤素；R4是C1-C4-烷基、C3-C4-烯基或C3-C4-炔基；R5是氢、C1-C4-烷基、C3-C4-烯基、C3-C4-炔基或一个C(═O)R51基团，其中R51是氢、C1-C4-烷基、C1-C4-卤代烷基、C1-C4-烷氧基或C1-C4-卤代烷氧基；R6是C1-C4-烷基、C1-C4-羟基烷基或C1-C4-卤代烷基；R7、R8独立地是氢、羟基、C1-C4-烷氧基、C1-C4-卤代烷氧基、C1-C4-烷基或C1-C4-卤代烷基；以及R9、R10独立地选自氢、卤素、氰基、硝基、C1-C4-烷基、C1-C4-卤代烷基、C2-C4-烯基、C1-C4-烷氧基和C1-C4-卤代烷氧基。
• PIPERAZINVERBINDUNGEN MIT HERBIZIDER WIRKUNG
  申请人：Basf Se

  公开号：EP2054394A2

  公开（公告）日：2009-05-06
• HERBIZID WIRKSAME ZUSAMMENSETZUNG
  申请人：BASF SE

  公开号：EP2157856A1

  公开（公告）日：2010-03-03