N-(2-diphenylphosphino)phenyl-N'-(8-quinolinyl)formamidine | 1403938-84-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2-diphenylphosphino)phenyl-N'-(8-quinolinyl)formamidine
• 英文别名: N-(2-diphenylphosphanylphenyl)-N'-quinolin-8-ylmethanimidamide
• CAS: 1403938-84-0
• 化学式: C₂₈H₂₂N₃P
• 分子量: 431.477
• InChiKey: GOEHCYRCRHULEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) 、 N-(2-diphenylphosphino)phenyl-N'-(8-quinolinyl)formamidine 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Amination of Aryl Iodides Catalyzed by a Palladium–Copper Complex Supported by a Chelate-Bridging Ligand

  摘要：

  Palladium-copper complexes supported by a new chelate-bridging ligand designed for a cooperative effect of two metals were synthesized The bimetallic complexes exhibited higher activities as catalysts for amination of aryl iodides than mononuclear catalyst.

  DOI：

  10.1021/om300902t

文献信息

• Synthesis of Dinuclear (μ-η³-Allyl)palladium(I) and -platinum(I) Complexes Supported by Chelate-Bridging Ligands
  作者：Yu Yamaguchi、Katsunori Yamanishi、Mitsuru Kondo、Naofumi Tsukada

  DOI：10.1021/om400557p

  日期：2013.9.9
• Amination of Aryl Iodides Catalyzed by a Palladium–Copper Complex Supported by a Chelate-Bridging Ligand
  作者：Naofumi Tsukada、Nozomi Ohnishi、Shiori Aono、Fusako Takahashi

  DOI：10.1021/om300902t

  日期：2012.11.12

  Palladium-copper complexes supported by a new chelate-bridging ligand designed for a cooperative effect of two metals were synthesized The bimetallic complexes exhibited higher activities as catalysts for amination of aryl iodides than mononuclear catalyst.