2-[2-(2-Aminoethyliminomethyl)phenoxy]acetic acid | 960596-84-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[2-(2-Aminoethyliminomethyl)phenoxy]acetic acid
• CAS: 960596-84-3
• 化学式: C₁₁H₁₄N₂O₃
• 分子量: 222.244
• InChiKey: XMRPDPNGAVRSMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.2
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  84.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 2-[2-(2-Aminoethyliminomethyl)phenoxy]acetic acid 、 水 以 甲醇 、 水 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  Molecular, supramolecular structure and catalytic activity of transition metal complexes of phenoxy acetic acid derivatives

  摘要：

  Six mononuclear complexes [M(L-1)(2)(H2O)(4)] (M = Co(II), 1a and M = Mn(II), 1b), [Cu(L-1)(2)(H2O)(2)] (1c) [Cu(L-1)(2)(H2O)(Py)(2)] (1d), [Cu(L-3)(H2O)Cl] center dot H2O (3a) and [Co(Sal)(H2O)(Py)(3)] center dot 2ClO(4) center dot H2O (3b) of phenoxyacetic acid derivatives and Schiff base were determined by single crystal X-ray diffraction. The Co(II) (1a) and Mn(II) (1b) complexes are isomorphous. X-ray crystal structural analyses reveal that these coordination complexes form polymeric structure via formation of different types of hydrogen bonding and K-stacking interactions in solid. Thermal analysis along with the powder X-ray diffraction data of these complexes shows the importance of the coordinated and/or crystal water molecules in stabilizing the MOF structure. Complexes 1a, 1e, 3a show marginal catalytic activity in the oxidation of olefins to epoxides in the presence of i-butyraldehyde and molecular oxygen. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.07.033

文献信息

• Molecular, supramolecular structure and catalytic activity of transition metal complexes of phenoxy acetic acid derivatives
  作者：Avijit Pramanik、Srinivas Abbina、Gopal Das

  DOI：10.1016/j.poly.2007.07.033

  日期：2007.11

  Six mononuclear complexes [M(L-1)(2)(H2O)(4)] (M = Co(II), 1a and M = Mn(II), 1b), [Cu(L-1)(2)(H2O)(2)] (1c) [Cu(L-1)(2)(H2O)(Py)(2)] (1d), [Cu(L-3)(H2O)Cl] center dot H2O (3a) and [Co(Sal)(H2O)(Py)(3)] center dot 2ClO(4) center dot H2O (3b) of phenoxyacetic acid derivatives and Schiff base were determined by single crystal X-ray diffraction. The Co(II) (1a) and Mn(II) (1b) complexes are isomorphous. X-ray crystal structural analyses reveal that these coordination complexes form polymeric structure via formation of different types of hydrogen bonding and K-stacking interactions in solid. Thermal analysis along with the powder X-ray diffraction data of these complexes shows the importance of the coordinated and/or crystal water molecules in stabilizing the MOF structure. Complexes 1a, 1e, 3a show marginal catalytic activity in the oxidation of olefins to epoxides in the presence of i-butyraldehyde and molecular oxygen. (C) 2007 Elsevier Ltd. All rights reserved.