bis(2-[(diethylamino)methyl]-4-methylphenolato)copper(II) | 78885-12-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2-[(diethylamino)methyl]-4-methylphenolato)copper(II)
• CAS: 78885-12-8；189257-04-3
• 化学式: C₂₄H₃₆CuN₂O₂
• 分子量: 448.108
• InChiKey: WMVKZFJVHQSUTF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-diethylaminomethyl-4-methylphenol 、 copper diacetate 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 以76%的产率得到bis(2-[(diethylamino)methyl]-4-methylphenolato)copper(II)
  参考文献：
  名称：

  Frolov, V. I.; Belov, P. S.; Lazarev, V. A., Russian Journal of Inorganic Chemistry, 1981, vol. 26, p. 1064 - 1065

  摘要：

  DOI：

文献信息

• Zinc(II) and copper(II) complexes of monoanionic chelating phenolato ligands containing an amine donor. Crystal and molecular structure of the (Et3NH)[ZnCl2L] and CuL2 compounds with L=2-[(diethylamino)methyl]-4-methylphenolate
  作者：Fabienne Connac、Nouzha Habaddi、Yolande Lucchese、Michèle Dartiguenave、Lydia Lamandé、Michel Sanchez、Michel Simard、André L. Beauchamp

  DOI：10.1016/s0020-1693(96)05425-4

  日期：1997.3

  The reaction of ZnCl2 with 2-[(diethylamino)methyl]phenol (AH) or 2-[(diethylamino)methyl]-4-methylphenol (BH) in the presence of NEt3 (1:1:1 ratio) gave good yields of the complexes (Et3NH) [ZnCl2L] (L = A (1), B (2)); Colourless crystals of 2 (monoclinic, P2(1)/c, a = 13.767, b = 11.650, c = 14.789 Angstrom, beta = 109.66 degrees, Z = 4, R = 0.042) contain monomeric tetrahedral zincate anions in which the metal is surrounded by two Cl atoms and one bidentate aminophenolato ligand. The Et3NH+ counter cation is hydrogen-bonded to the coordinated phenolate oxygen, Brown CuL2 complexes (L = A (3), B (4)) were obtained by reacting Cu(NO3)(2) . 3H(2)O, CuCl2 . 2H(2)O or CuSO4 . 3H(2)O with AH and BH, respectively, in the presence of NEt3 in a 1:2:2 Cu:ligand:NEt3 ratio, Crystals of 4 (monoclinic, P2(1)/c, a = 8.165, b = 14.798, c = 9.481 Angstrom, beta = 90.91 degrees, Z = 2, R = 0.048) contain monomeric square-planar copper centres surrounded by two bidentate aminophenolato ligands in a trans arrangement. The presence of relatively bulky ethyl substituents on the amino group favours the monomeric chelates by preventing the formation of phenolate-bridged polynuclear arrangements.