| 588701-74-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 588701-74-0
• 化学式: C₂₈H₂₆CuN₂O₄
• 分子量: 518.071
• InChiKey: OZDFZPPDTQCINK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2,2'-联苯二甲酸 、 邻甲苯胺 以 乙醇 、 水 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  Synthesis, Magnetic, and Spectral Studies of Some Mixed‐Ligand Complexes of Copper(II) Involving Diphenic Acid and Pyridine or Aniline Derivatives

  摘要：

  New mixed-ligand hexa-coordinated diphenato complexes of copper(II) having the general formula [Cu(DPA)(L)(2)], where DPAH(2) = diphenic acid and L = nicotinamide (NICA), 2-cyanopyridine (2-CPY), 3-cyanopyridine (3-CPY) and 4-cyanopyridine (4-CPY) or aniline derivatives, such as, o-toluidine (o-TD), in-toluidine (m-TD) or o-phenetidine (o-PD), have been prepared by the interaction of an aqueous solution of cupric chloride and ethanolic solutions of diphenic acid and the corresponding ligand L, in the mole ratio of 1:1:2. The resulting products have been characterized on the basis of analytical data, molar conductances, magnetic measurements, infrared, electronic and electron spin resonance spectral studies. All of the complexes are thermally stable and behave as non-electrolytes. A square-planar geometry has been suggested for these complexes.

  DOI：

  10.1081/sim-120020331